57623-20-8Relevant academic research and scientific papers
PHOTOSENSITIZED Oxidation of Furans. Part 4. Influence of the Substituents on the Behaviour of the endo-Peroxides of Furans
Graziano, M. Liliana,Iesce, M. Rosaria,Scarpati, Rachele
, p. 2007 - 2012 (2007/10/02)
A comparison of the ehaviour of endo-peroxides of the β-furoic esters (1a, b and d-f) and of the furans (1c or g), with the same 2,5-substituents, shows that the thermal instability of these compounds is related to the electron density in the bicyclic unsaturated ring.This also accounts for the higher stability of the alkyl-substituted endo-peroxides (1a-c) as compared with that of the aryl-substituted derivatives (1d-g), as well as for the different course of the thermal conversion in the two series.
