57997-56-5Relevant articles and documents
Thermochemical Properties of Triphenylantimony Dibenzoate Ph3Sb(OC(O)Ph)2
Knyazev, A. V.,Lyakaev, D. V.,Markin, A. V.,Sharutin, V. V.,Sharutina, O. K.,Smirnova, N. N.
, p. 1776 - 1779 (2020)
Abstract: The energy of combustion of crystalline triphenylantimony dibenzoate is measured using an isoperibolic combustion calorimeter with a static bomb at T = 298.15 K. The experimental data show that the standard enthalpy of combustion of this substance in the crystalline state is calculated for T = 298.15 K. Standard functions ?fH° and ?fG° of the formation of the compound in the crystalline state are calculated for T = 298.15 K.
Pd-catalyzed C-arylation of unsaturated compounds with pentavalent triarylantimony dicarboxylates
Moiseev, Dmitry V.,Gushchin, Aleksey V.,Shavirin, Andrey S.,Kursky, Yury A.,Dodonov, Viktor A.
, p. 176 - 184 (2007/10/03)
Triarylantimony (V) derivatives Ar3SbX2 (X = Hal or acyloxy) were prepared by reaction of Ar3Sb with equimolar amounts of a peroxide ROOH (R = t-Bu, H) in the presence of an acid or an anhydride in good to excellent yields. Ar3Sb(O2CR)2 are mild and efficient C-arylation reagents of unsaturated compounds (methyl acrylate, styrene, 2-phenylpropene and acrylonitrile) under palladium catalysis at 50 °C, with PdCl2 being the most effective catalyst. Ar3SbHal2 do not react under these conditions.
Electrochemistry of hypervalent compounds - V. Anodic oxidation of trivalent organoantimony and organobismuth compounds
Fuchigami, Toshio,Miyazaki, Motoko
, p. 1979 - 1984 (2008/10/08)
Anodic oxidation of triphenylantimony in the presence of various oxygen nucleophiles or halide ions provided the corresponding hypervalent compounds having Sb - Y bonds (Y = RCOO, F, Cl, Br) in good yields. On the contrary, anodic oxidation of triphenylbi
