6222-17-9Relevant articles and documents
Cobalt-Catalyzed Csp3?Csp3Homocoupling
Cai, Yingxiao,Qian, Xin,Gosmini, Corinne
supporting information, p. 2427 - 2430 (2016/08/16)
An efficient and easy method for Csp3?Csp3homocoupling was developed using cobalt bromide as catalyst. A series of functionalized alkyl bromides and alkyl chlorides were coupled in high yields under mild conditions. This reaction seems to involve a radical intermediate. (Figure presented.).
Lipase-catalysed selective monoacylation of 1,n-diols with vinyl acetate
Framis, Victoria,Camps, Francisco,Clapés, Pere
, p. 5031 - 5033 (2007/10/03)
A simple enzymatic methodology for the selective monoacetylation of 1,n-diols (n=5,8) using vinyl acetate is reported. Monoacetylation excesses of 81-87% at 74-90% 1,n-diol conversions were obtained in toluene and diisopropyl ether using Thermomyces lanuginosus lipase (TLL) immobilised on polypropylene powder as catalyst.
Omega-hydrofluoroalkyl ethers, precursor carboxylic acids and derivatives thereof, and their preparation and application
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Page 14, (2010/01/31)
Normally liquid, omega-hydrofluoroalkyl ether compounds (and selected mixtures thereof) have a saturated perfluoroaliphatic chain of carbon atoms interrupted by one or more ether oxygen atoms. The compounds can be prepare, e.g. by decarboxylation of the corresponding fluoroalkyl ether carboxylic acids and are useful, e.g., in cleaning and drying applications.
