63444-57-5

Basic information

• Product Name: Methanone, (3-ethenylphenyl)phenyl-
• Synonyms: m-vinylbenzophenone;3-benzoylstyrene;3-ethenylphenyl phenyl ketone;Methanone,(3-ethenylphenyl)phenyl;phenyl(m-vinylphenyl)ketone;(phenyl)(3-vinylphenyl)ketone;3-vinylbenzophenone;3-ethenylbenzophenone
• CAS NO: 63444-57-5
• Molecular Formula: C15H12O
• Molecular Weight: 208.26
• Mol File: 63444-57-5.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Methanone, (3-ethenylphenyl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (3-ethenylphenyl)phenyl-(63444-57-5)
• EPA Substance Registry System: Methanone, (3-ethenylphenyl)phenyl-(63444-57-5)

Safety Data

• Hazardous Substances Data: 63444-57-5(Hazardous Substances Data)

Upstream product

• 2835-78-1 3-amino benzophenone 
• 108-05-4 vinyl acetate 
• 1016-77-9 3-bromobenzophenone 
• 22071-15-4 ketoprofen 
• 2241846-02-4 1,3-dioxoisoindolin-2-yl 2-(3-benzoylphenyl)propanoate 
• 98-86-2 acetophenone 
• 65-85-0 benzoic acid 
• 2039-86-3 3-bromostyrene 
• 98-88-4 benzoyl chloride 
• 451-40-1 phenyl benzyl ketone 
• 108-86-1 bromobenzene 
• 71-43-2 benzene 
• 1711-09-7 3-bromobenzoyl chloride 
• 201230-82-2 carbon monoxide 

Downstream Products

• 22071-15-4 ketoprofen 
• 22161-81-5 S-ketoprofen 
• 160334-26-9 (S)-2-(3-benzoylphenyl)-N-phenylpropanamide 

Relevant articles and documents

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Vinyl Acetate in Dimethyl Isosorbide as a Sustainable Solvent

A nickel-catalyzed reductive cross-coupling has been achieved using (hetero)aryl bromides and vinyl acetate as the coupling partners. This mild, applicable method provides a reliable access to a variety of vinyl arenes, heteroarenes, and benzoheterocycles, which should expand the chemical space of precursors to fine chemicals and polymers. Importantly, a sustainable solvent, dimethyl isosorbide, is used, making this protocol more attractive from the point of view of green chemistry.

A process for the preparation and synthetic ChondriamideA and ChondriamideC method (by machine translation)

The invention provides a process for the preparation of synthetic Chondriamide A and Chondriamide C and method, wherein the invention provides a process for the preparation, including: formula (I) compounds of structure, palladium catalyst, phosphorus ligand, alkali and organic solvent at room temperature the illumination reaction, formula (II) structure obtained olefin; wherein through the selection of a particular phosphorus ligand; make the method of the invention can be under the photocatalysis, room temperature to realize high-efficient catalytic conversion, and the mild reaction conditions, simple operation, in line with the development of green environment-friendly chemical requirements, and the range of choice of substrate and functional group compatibility has more universal, and has outstanding chemical selectivity; and the method can be successfully applied to complex molecular introducing carbon-carbon double bond to the programme, to optimize a part of the drug molecular synthesis strategy, improve the synthesis efficiency, reduce the cost, with industrial synthetic value and prospects. (by machine translation)

Palladium-catalyzed acylative cross-coupling of amides with diarylborinic acids and sodium tetraarylborates

Abstract A general and efficient acylative Suzuki coupling of active amides with diarylborinic acids has been achieved by using 1 mol% Pd(PCy3)2Cl2/0.6 mol% PCy3 as catalyst system taking advantage of modifiable reactivities of acyl-nitrogen bonds of amides. Both electronic and steric influences from either aryl or acyl counterparts on the coupling proved to be negligible or small. A variety of aryl ketones including sterically hindered ones could be synthesized by the coupling of diarylborinic acids in good to excellent yields. Sodium tetraarylborates could also be used as high atom-economy aryl source in the palladium-catalyzed cross-coupling with active amides.