65119-09-7Relevant articles and documents
C,N-chelated diaminocarbene platinum(II) complexes derived from 3,4-diaryl-1H-pyrrol-2,5-diimines and cis-dichlorobis(isonitrile)platinum(II): Synthesis, cytotoxicity, and catalytic activity in hydrosilylation reactions
Afanasenko, Anastasiia M.,Boyarskaya, Irina A.,Chulkova, Tatiana G.,Elinson, Michail N.,Haukka, Matti,Islamova, Regina M.,Keppler, Bernhard K.,Legin, Anton A.,Selivanov, Stanislav I.,Vereshchagin, Anatoly N.
, (2020)
The reaction of 3,4-diaryl-1H-pyrrol-2,5-diimines with cis-dichlorobis(isonitrile)platinum(II) affords the C,N-chelated diaminocarbene platinum(II) complexes, which have been fully characterized including molecular spectroscopy, single crystal X-ray diffr
Dichloro(ethylenediamine)platinum(II), a water-soluble analog of the antitumor cisplatin, as a heterogeneous catalyst for a stereoselective hydrosilylation of alkynes under neat conditions
Fotie, Jean,Enechojo Agbo, Mercy,Qu, Fengrui,Tolar, Trevor
supporting information, (2020/08/13)
A stereoselective method for the hydrosilylation of internal and terminal alkynes under heterogeneous catalysis by dichloro(ethylenediamine)platinum(II) is discussed. This commercially available platinum complex operates under neat conditions at 90 °C, pr
The effect of an acylphosphine ligand on the rhodium-catalyzed hydrosilylation of alkenes
Li, Jiayun,Yang, Chuang,Bai, Ying,Yang, Xiaoling,Liu, Yu,Peng, Jiajian
, p. 7 - 11 (2018/01/01)
We synthesized a series of acylphosphines and investigated the hydrosilylation of alkenes that were catalyzed using RhCl3/acylphosphine. The results indicated that RhCl3/(diphenylphosphino) (phenyl)methanone exhibited higher activity as well as higher levels of β–adduct selectivity.