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67442-07-3

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67442-07-3 Usage

Uses

2-Chloro-N-methoxy-N-methylacetamide is used in the preparation of 2-heptyl-3-hydroxy-4(1H)-quinolone (Pseudomonas quinolone signal or PQS) and structurally related 2-alkyl-4-quinolones having biological activity, 2-(benzo[d]thiazol-2-ylsulfonyl)-N-methoxy-N-methylacetamide and α-chloro-ketone, starting reagent for the one-pot synthesis of 2-heptyl-3-hydroxyl-4(1H)-quinolone (PQS), signaling molecule in the quorum sensing of Pseudomonas aeruginosa.

General Description

2-Chloro-N-methoxy-N-methylacetamide is a Weinreb amide.

Check Digit Verification of cas no

The CAS Registry Mumber 67442-07-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,7,4,4 and 2 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 67442-07:
(7*6)+(6*7)+(5*4)+(4*4)+(3*2)+(2*0)+(1*7)=133
133 % 10 = 3
So 67442-07-3 is a valid CAS Registry Number.
InChI:InChI=1/C4H8ClNO2/c1-6(8-2)4(7)3-5/h3H2,1-2H3

67442-07-3 Well-known Company Product Price

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  • Alfa Aesar

  • (L17048)  2-Chloro-N-methoxy-N-methylacetamide, 98%   

  • 67442-07-3

  • 5g

  • 746.0CNY

  • Detail
  • Alfa Aesar

  • (L17048)  2-Chloro-N-methoxy-N-methylacetamide, 98%   

  • 67442-07-3

  • 25g

  • 2470.0CNY

  • Detail

67442-07-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Chloro-N-methoxy-N-methylacetamide

1.2 Other means of identification

Product number -
Other names 2-CHLORO-N-METHOXY-N-METHYLACETAMIDE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:67442-07-3 SDS

67442-07-3Relevant articles and documents

Substituted Tetraethynylethylene–Tetravinylethylene Hybrids

Connor, Kieran P. E.,Horvath, Kelsey L.,Magann, Nicholas L.,Sherburn, Michael S.,Sowden, Madison J.,Westley, Erin

supporting information, p. 977 - 986 (2022/02/03)

A general synthetic approach to molecular structures that are hybrids of tetraethynylethylene (TEE) and tetravinylethylene (TVE) is reported. The synthesis permits the controlled preparation of many previously inaccessible structures, including examples w

Concise and Efficient Synthesis of [6]-Paradol

Shi, Xiang,Xia, Tiantian,McKamey, Brooke E.,Wu, Xian,Sun, Yue,Zhou, Weifeng,Zhang, Guangyan

, p. 1360 - 1365 (2021/06/21)

An efficient synthesis of [6]-paradol (1) has been performed in four steps with a 72.0% overall yield. The present method highlights commercially available materials, convenient isolation with multiple crystallization without involving column chromatography, and a high-purity product (more than 99.2%), and it is amenable to large-scale synthesis.

Quaternary Charge-Transfer Complex Enables Photoenzymatic Intermolecular Hydroalkylation of Olefins

Page, Claire G.,Cooper, Simon J.,Dehovitz, Jacob S.,Oblinsky, Daniel G.,Biegasiewicz, Kyle F.,Antropow, Alyssa H.,Armbrust, Kurt W.,Ellis, J. Michael,Hamann, Lawrence G.,Horn, Evan J.,Oberg, Kevin M.,Scholes, Gregory D.,Hyster, Todd K.

supporting information, p. 97 - 102 (2021/01/12)

Intermolecular C-C bond-forming reactions are underdeveloped transformations in the field of biocatalysis. Here we report a photoenzymatic intermolecular hydroalkylation of olefins catalyzed by flavin-dependent 'ene'-reductases. Radical initiation occurs via photoexcitation of a rare high-order enzyme-templated charge-transfer complex that forms between an alkene, α-chloroamide, and flavin hydroquinone. This unique mechanism ensures that radical formation only occurs when both substrates are present within the protein active site. This active site can control the radical terminating hydrogen atom transfer, enabling the synthesis of enantioenriched γ-stereogenic amides. This work highlights the potential for photoenzymatic catalysis to enable new biocatalytic transformations via previously unknown electron transfer mechanisms.

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