70111-04-5

Basic information

• Product Name: 1,2-Ethanediol, 1-phenyl-, 2-benzoate, (S)-
• CAS NO: 70111-04-5
• Molecular Formula: C15H14O3
• Molecular Weight: 242.274
• Mol File: 70111-04-5.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 1,2-Ethanediol, 1-phenyl-, 2-benzoate, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Ethanediol, 1-phenyl-, 2-benzoate, (S)-(70111-04-5)
• EPA Substance Registry System: 1,2-Ethanediol, 1-phenyl-, 2-benzoate, (S)-(70111-04-5)

Safety Data

• Hazardous Substances Data: 70111-04-5(Hazardous Substances Data)

Upstream product

• 33868-50-7 phenacyl benzoate 
• 93-56-1 phenylethane 1,2-diol 
• 98-88-4 benzoyl chloride 
• 100-52-7 benzaldehyde 
• 25779-13-9 (S)-1-phenyl-1,2-ethanediol 
• 98-86-2 acetophenone 
• 501-53-1 benzyl chloroformate 

Downstream Products

• 426836-30-8 (S)-[2-(methoxymethoxy)-2-phenyl]ethyl benzoate 
• 499203-37-1 (S)-1-[(2-benzoyloxy-1-phenylethoxy)methyl]cytosine 
• 499203-38-2 (S)-9-[(2-benzoyloxy-1-phenylethoxy)methyl]adenine 
• 426836-31-9 (S)-[2-(acetoxymethoxy)-2-phenyl]ethyl benzoate 
• 426836-32-0 (S)-1-[(2-benzoyloxy-1-phenylethoxy)methyl]thymine 
• 426836-34-2 (S)-9-[(2-benzoyloxy-1-phenylethoxy)methyl]guanine 

Relevant articles and documents

Kinetic Resolution of 1,2-Diols via NHC-Catalyzed Site-Selective Esterification

A kinetic resolution of 1,2-diols bearing both a secondary and a primary alcohol motif through an N-heterocyclic carbene-catalyzed oxidative acylation reaction has been developed. A site- and enantioselective esterification reaction is involved for this process. Both the monoacylated diols obtained and the remaining enantioenriched 1,2-diols are versatile building blocks for the preparation of functional molecules with proven biological activities.

Palladium-catalyzed asymmetric hydrogenation of α-acyloxy-1- arylethanones

First hand: The first example of a palladium-catalyzed asymmetric hydrogenation of α-acyloxy ketones (1) was accomplished to give the hydrogenated products 2 with by far the highest catalytic efficiency in up to quantitative conversions and excellent enantioselectivities. The hydrogenated products could serve as important intermediates for the preparation of many drug candidates. TFE=2,2,2-trifluoroethanol. Copyright

Synthesis, conformation and antiviral activity of nucleoside analogues with the (2-hydroxy-1-phenylethoxy)methyl glycone - A family of nucleoside analogues related to d4T and aciclovir

A complete family of acyclic nucleoside analogues has been obtained by combining the (2-hydroxy-1-phenylethoxy)methyl glycone with the nucleoside bases adenine, guanine, cytosine, thymine and uracil. In each case both optical antipodes have been prepared