709-25-1

Basic information

• Product Name: N-(2-methylallyl)benzamide
• Synonyms: N-(2-methylallyl)benzamide
• CAS NO: 709-25-1
• Molecular Weight: 175.23
• Mol File: 709-25-1.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: N-(2-methylallyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-methylallyl)benzamide(709-25-1)
• EPA Substance Registry System: N-(2-methylallyl)benzamide(709-25-1)

Safety Data

• Hazardous Substances Data: 709-25-1(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 2878-14-0 2-methylallylamin 
• 2719-27-9 cyclohexanylcarbonyl chloride 
• 21384-58-7 2,2-dimethylaziridin-1-yl-phenylmethanone 
• 1663-39-4 tert-Butyl acrylate 
• 65-85-0 benzoic acid 
• 120-12-7 anthracene 
• 64-19-7 acetic acid 
• 519-73-3 triphenylmethane 
• 91-20-3 naphthalene 
• 108-98-5 thiophenol 
• 86-29-3 Diphenylacetonitrile 
• 67-56-1 methanol 
• 19312-06-2 4,5-dihydro-4,4-dimethyl-2-phenoxazole 

Downstream Products

• 1359180-50-9 (R)-5-(fluoromethyl)-5-methyl-2-phenyl-4,5-dihydrooxazole 
• 113261-11-3 5-methyl-2-phenyl-5-phenylthiomethyl-4,5-dihydro-1,3-oxazole 
• 137521-27-8 N-benzoyl-4-methylproline 
• 137521-44-9 methyl N-benzoyl-4-methylprolinate 
• 137521-30-3 3-methyl-4-(benzoylamino)butanol 
• 133523-83-8 5-Methyl-2-phenyl-5-phenylselanylmethyl-4,5-dihydro-thiazole 
• 133523-70-3 5,6-dihydro-5-methyl-2-phenyl-4H-1,3-thiazine 
• 14599-03-2 methyl 2-benzamido-3-methylbutanoate 
• 37950-61-1 5,5-Dimethyl-2-phenyl-thiazoline 
• 115859-57-9 1-benzoyl-2-formyl-4-methylpyrrolidine 
• 115859-58-0 (3-methylpyrrolidin-1-yl)(phenyl)methanone 
• 5202-81-3 N-(2-methyl-1-propen-1-yl)benzamide 
• 113261-12-4 5-methyl-2-phenyl-5-propylthiomethyl-4,5-dihydro-1,3-oxazole 

Relevant articles and documents

Electrochemical oxidative cyclization of: N -allylcarboxamides: Efficient synthesis of halogenated oxazolines

Herein, we reported an efficient and sustainable intramolecular electrochemical cyclization of N-allylcarboxamides for the synthesis of various halogenated oxazolines. This method was conducted in a simple undivided cell by employing lithium halogen salts

Aminoxyl-Catalyzed Electrochemical Diazidation of Alkenes Mediated by a Metastable Charge-Transfer Complex

We report the development of a new aminoxyl radical catalyst, CHAMPO, for the electrochemical diazidation of alkenes. Mediated by an anodically generated charge-transfer complex in the form of CHAMPO-N3, radical diazidation was achieved across a broad scope of alkenes without the need for a transition metal catalyst or a chemical oxidant. Mechanistic data support a dual catalytic role for the aminoxyl serving as both a single-electron oxidant and a radical group transfer agent.

Copper-Catalyzed Divergent Trifluoromethylation/Cyclization of Unactivated Alkenes

Most of the precedent copper-catalyzed trifluoromethylation reactions of unactivated alkenes concern terminal alkenes, and these processes are terminated in elimination, or nucleophilic addition, or semipinacol rearrangement, or C-H bond functionalization steps. In this study, we develop a trifluoromethylation method for both unactivated terminal and internal alkenes to enable divergent late-stage radical cyclization and achieve high molecular complexity. These cyclizations are well consistent with Baldwin's rule. Furthermore, a kinetic isotope effect (KIE) study and control reactions were conducted, and a plausible mechanism is proposed.