7205-58-5

Basic information

• Product Name: Benzene, 1-(ethylthio)-4-methoxy-
• CAS NO: 7205-58-5
• Molecular Formula: C9H12OS
• Molecular Weight: 168.26
• Mol File: 7205-58-5.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(ethylthio)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(ethylthio)-4-methoxy-(7205-58-5)
• EPA Substance Registry System: Benzene, 1-(ethylthio)-4-methoxy-(7205-58-5)

Safety Data

• Hazardous Substances Data: 7205-58-5(Hazardous Substances Data)

Upstream product

• 93-89-0 benzoic acid ethyl ester 
• 5335-87-5 4,4'-dimethoxyphenyl disulfide 
• 696-63-9 4-Methoxybenzenethiol 
• 696-62-8 para-iodoanisole 
• 811-51-8 sodium thioethylate 
• 75-08-1 ethanethiol 
• 106-54-7 p-Chlorothiophenol 
• 1879-16-9 1-methoxy-4-methylsulfanyl-benzene 
• 123-09-1 4-chlorophenyl methyl sulfide 
• 7205-62-1 1-chloro-4-(isopropylthio)benzene 
• 106-46-7 para-dichlorobenzene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 97-93-8 triethylaluminum 
• 98-68-0 4-methoxy-phenyl-sulphonyl chloride 

Downstream Products

• 1616280-27-3 C₂₉H₂₉N₃O₆S 
• 1616280-24-0 C₃₀H₃₁N₃O₆S 
• 1616280-10-4 5-{5-amino-2-[4-(ethylsulfonyl)phenoxy]phenyl}-1-methylpyrrolidin-2-one 
• 1616280-07-9 5-{5-amino-2-[4-(ethylsulfonyl)phenoxy]-4-iodophenyl}-1-methylpyrrolidin-2-one 
• 1616280-05-7 5-{2-[4-(ethylsulfonyl)phenoxy]-5-nitrophenyl}-1-methylpyrrolidin-2-one 
• 859537-79-4 4-hydroxy-phenyl-ethylsulfone 
• 1616280-18-2 C₂₂H₂₅IN₂O₆S 
• 1616280-16-0 C₂₂H₂₅IN₂O₆S 
• 7205-68-7 1-(ethylsulfinyl)-4-methoxybenzene 
• 150811-28-2 1-Methoxy-2-methyl-4-(isopropylthio)benzene 
• 50390-80-2 4-(Ethylthio)-1-methoxy-2-methylbenzene 
• 7205-61-0 1-methoxy-4-<(1-methylethyl)thio>-benzene 
• 74-85-1 ethene 
• 5633-57-8 1-methoxy-4-(phenylsulfanyl)benzene 

Relevant articles and documents

Production of Alkyl Aryl Sulfides from Aromatic Disulfides and Alkyl Carboxylates via a Disilathiane–Disulfide Interchange Reaction

The results of this study show that disilathiane is an effective mediator in the synthesis of alkyl aryl sulfides with disulfides and alkyl carboxylates. Mechanistic studies suggest that disilathiane promotes cleavage of the sulfur–sulfur bond of disulfides to generate thiosilane as a key intermediate. Diselenides were also applicable to this transformation to produce the corresponding selenides.

Nickel-Catalyzed Reversible Functional Group Metathesis between Aryl Nitriles and Aryl Thioethers

We describe a new functional group metathesis between aryl nitriles and aryl thioethers. The catalytic system nickel/dcype is essential to achieve this fully reversible transformation in good to excellent yields. Furthermore, the cyanide- and thiol-free reaction shows high functional group tolerance and great efficiency for the late-stage derivatization of commercial molecules. Finally, synthetic applications demonstrate its versatility and utility in multistep synthesis.

Site-Selective C?S Bond Formation at C?Br over C?OTf and C?Cl Enabled by an Air-Stable, Easily Recoverable, and Recyclable Palladium(I) Catalyst

This report widens the repertoire of emerging PdI catalysis to carbon–heteroatom, that is, C?S bond formation. While Pd0-catalyzed protocols may suffer from the formation of poisonous sulfide-bound off-cycle intermediates and lack of selectivity, the mechanistically diverse PdI catalysis concept circumvents these challenges and allows for C?S bond formation (S–aryl and S–alkyl) of a wide range of aryl halides. Site-selective thiolations of C?Br sites in the presence of C?Cl and C?OTf were achieved in a general and a priori predictable fashion. Computational, spectroscopic, X-ray, and reactivity data support dinuclear PdI catalysis to be operative. Contrary to air-sensitive Pd0, the active PdI species was easily recovered in the open atmosphere and subjected to multiple rounds of recycling.