73172-56-2

Basic information

• Product Name: ETHYL 5-OXO-5-PHENYLVALERATE
• Synonyms: ETHYL 5-OXO-5-PHENYLVALERATE
• CAS NO: 73172-56-2
• Molecular Formula: C₁₃H₁₆O₃
• Molecular Weight: 220.26
• Mol File: 73172-56-2.mol
• Article Data: 34

Chemical Properties

• Boiling Point: 337.1°C at 760 mmHg
• Flash Point: 147.4°C
• Appearance: /
• Density: 1.064g/cm³
• Vapor Pressure: 0.000108mmHg at 25°C
• Refractive Index: 1.503
• CAS DataBase Reference: ETHYL 5-OXO-5-PHENYLVALERATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL 5-OXO-5-PHENYLVALERATE(73172-56-2)
• EPA Substance Registry System: ETHYL 5-OXO-5-PHENYLVALERATE(73172-56-2)

Safety Data

• Hazardous Substances Data: 73172-56-2(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Chemistry Letters, 17, p. 1141, 1988Tetrahedron Letters, 29, p. 4513, 1988 DOI: 10.1016/S0040-4039(00)80534-1

InChI:InChI=1/C13H16O3/c1-2-16-13(15)10-6-9-12(14)11-7-4-3-5-8-11/h3-5,7-8H,2,6,9-10H2,1H3

Upstream product

• 4406-72-8 2-phenyl[1,3,2]dioxaborolane 
• 3709-23-7 <3-Phenyl-3-oxo-propyl>-malonsaeure-diethylester 
• 98-88-4 benzoyl chloride 
• 151073-69-7 (4-ethoxy-4-oxobutyl)zinc(II) bromide 
• 64-17-5 ethanol 
• 1501-05-9 5-oxo-5-phenylvaleric acid 
• 935-64-8 1-phenyl-1-cyclobutanol 
• 201230-82-2 carbon monoxide 
• 108-55-4 glutaric anhydride, 
• 100-58-3 phenylmagnesium bromide 
• 100-42-5 styrene 
• 1518-20-3 ethyl trans-2-benzoylcyclopropane-1-carboxylate 
• 93-91-4 1-phenylbutan-1,3-dione 
• 140-88-5 ethyl acrylate 

Downstream Products

• 139527-18-7 Ethyl 5-hydroxy-5-phenylpentanoate 
• 250602-58-5 ethyl (E)-5-(hydroxyimino)-5-phenylpentanoate 
• 94800-94-9 (R)-ethyl 5-hydroxy-5-phenylpentanoate 
• 41419-25-4 6-phenylpiperidin-2-one 

Relevant articles and documents

Manganese-catalyzed ring-opening carbonylation of cyclobutanol derivatives

Herein, we report a manganese-catalyzed ring-opening carbonylation of cyclobutanol derivatives through cyclic C–C bond cleavage. The reaction happens via a radical-mediated pathway to selectively generate 1,5-ketoesters. A variety of substrates with subst

Inorganic alkali catalytic 1, 5 - ketonic ester apperception compound synthesis method

The invention discloses a synthesis method for a 1,5-ketonic ester compound under catalyzing of inorganic base. The synthesis method comprises the following steps: taking a compound of the general formula I as a raw material, taking inorganic base as a ca

Sequential Michael addition/retro-Claisen condensation of aromatic β-diketones with α,β-unsaturated esters: An approach to obtain 1,5-ketoesters

A K2CO3-catalyzed one-pot protocol involving sequential C-C bond formation and cleavage of aromatic β-diketones with α,β-unsaturated esters is developed to obtain 1,5-ketoesters. The sequential reaction via Michael addition and retro-Claisen condensation proceeds smoothly under mild conditions in up to 98% isolated yield. The mechanism study disclosed that the cascade process involved C-C bond cleavage of aromatic β-diketone as a phenacyl donor under alcoholic alkalescent conditions.