7355-77-3Relevant academic research and scientific papers
Syntheses, crystal structures and DNA-binding studies of Cu(II) and Zn(II) complexes bearing asymmetrical aroylhydrazone ligand
Li, Yueqin,Yang, Zhiwei,Zhou, Minya,He, Jing,Wang, Xuehong,Wu, Yanlong,Wang, Zhuye
, p. 818 - 828 (2016/12/16)
Zn(II) and Cu(II) complexes with benzophenone benzoyl hydrazone (HBBH) and benzophenone salicylylhydrazone (HBSH) have been synthesized and characterized by different physico-chemical and spectroscopic techniques (UV-vis, IR and NMR). The molecular struct
Mild, Stereoselective, and Highly Efficient Synthesis of N-Acylhydrazones Mediated by CeCl3·7H2O in a Broad Range of Solvents
Dos Santos Filho, José Maurício
supporting information, p. 6411 - 6417 (2016/02/18)
In a mild and practical approach, hydrazides and aldehydes underwent condensation reactions that were mediated by cerium(III) chloride to be rapidly converted into N-acylhydrazones. This method uses a minimal catalytic amount of cerium(III), is stereosele
Photochemistry of arylhydrazides in solution
Belov,Rogachev,Tkachenko,Smirnov,Aldoshin
, p. 666 - 668 (2007/10/03)
The photochemical reactions of arylhydrazides ArCONHN=CHR in solution were studied. The main photochemical process was shown to be trans - cis isomerization with a quantum yield of 0.2-0.8 and an activation energy of 21-24 kcal mol-1.
Unsaturated Compounds containing Nitrogen. Part 4. Further Reactions of 1-Chloro-2,3-diazabutadienes with S-Nucleophiles
Flowers, William T.,Robinson, John F.,Taylor, David R.,Tipping, Anthony E.
, p. 349 - 355 (2007/10/02)
1-Chloro-1,4-diaryl-2,3-diazabutadienes (Ar1CCl=NN=CHAr2), prepared by the reaction of thionyl chloride with aroylhydrazones (Ar1CONHN=CHAr2), react with thiosemicarbazide or thiocarbohydrazide to give 2-arylidenehydrazino-5-aryl-1,3,4-thiadiazoles, and with potassium thiocyanate to give 1-thiocyanato-1,4-diaryl-2,3-diazabutadienes which isomerize thermally to arylideneamino-5-aryl-1,3,4-thiadiazoles. 1-Chloro-1,4-diphenyl-2,3-diazabutadiene reacts with potassium ethylxanthate to give a 1-ethylxanthyl-2,3-diazabutadiene which on pyrolysis yields 2,5-diphenyl-1,3,4-thiadiazole.
