7646-81-3Relevant articles and documents
Direct, oxidative halogenation of diaryl- or dialkylphosphine oxides with (dihaloiodo)arenes
Eljo, Jasmin,Murphy, Graham K.
supporting information, p. 2965 - 2969 (2018/06/30)
The oxidative halogenation of diaryl- or dialkylphosphine oxides with the hypervalent iodine reagents (difluoroiodo)toluene (p-TolIF2, 1) and (dichloroiodo)benzene (PhICl2, 2) is reported. Phosphoric fluorides could be recovered in 32–75% yield, or they could be trapped with EtOH to give the corresponding phosphinate in typically good yield. Phosphoric chlorides were not readily isolable, and were trapped with alcohol and amine nucleophiles, giving diaryl- or dialkylphos-phinates and phosphinamides in up to 90% yield.
Reactivity of diacyloxyiodobenzenes toward trivalent phosphorus nucleophiles
Makowiec, Slawomir,Rachon, Janusz
, p. 352 - 359 (2007/10/03)
The reaction of diacyloxyiodobenzenes and tetravalent phosphorus nucleophiles was investigated. It was established that both H-phosphonates and secondary phosphine oxides react with diacetoxyiodobenzene in alcohols in the presence of sodium alcoholates yi
ACID CATALYSIS IN THE HYDROPHOSPHORYLATION OF OLEFINS
Nifant'ev, E. E.,Magdeeva, R. K.,Shchepet'eva, N. P.
, p. 1416 - 1423 (2007/10/02)
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