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Palladium Chloride Pdcl2 CAS: 7647-10-1
Cas No: 7647-10-1
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High Quality 99% Pure Lpalladium Chloride PdCl2 7647-10-1
Cas No: 7647-10-1
No Data 5 Gram 10000 Kilogram/Day Xi'an ZB Biotech Co., Ltd. Contact Supplier
In stock Pd catalyst Palladium Chloride PdCl2
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High purity Palladium chloride PdCL2 with high quality and best price cas:7647-10-1
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CAS:7647-10-1 Palladium chloride
Cas No: 7647-10-1
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Palladium chloride
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Palladium(II) chloride
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Top sell Palladium chloride CAS:7647-10-1
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USD $ 0.32-0.98 / Gram 1 Gram 1 Metric Ton/Day WUHAN MULEI NEW MATERIAL CO., LTD Contact Supplier
Palladium chloride
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Palladous chloride
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7647-10-1 Usage

Chemical Properties

Palladium chloride is a dark brown powder, hygroscopic (absorbs moisture from the air). It is incompatible with acids, aluminium, ammonia, magnesium, nitrates, zinc, heat, thiocyanates, and organic solvents. Thermal decomposition of palladium chloride may release chlorine, hydrogen chloride, and oxides of palladium. It is used as a catalyst, photographic, and electroplating reagent. Palladium and its alloys are used as catalysts in the (petro)chemical and, above all, in the automotive industries. Applications of palladium compounds for electronics and electrical technology include use in metallisation processes (thick film paste), electrical contacts and switching systems, in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar. Palladium chloride is a stable chemical substance and is incompatible with strong oxidising agents.

Uses

suzuki reaction

Reactivity Profile

Palladium chloride is a weak oxidizing agent. Palladium chloride is reduced in solution by hydrogen or carbon monoxide to metallic palladium. . Decomposed at high temperatures to metallic palladium and chlorine.

Purification Methods

The anhydrous salt is insoluble in H2O and dissolves in HCl with difficulty. The dihydrate forms red hygroscopic crystals that are readily reduced to Pd. Dissolve it in conc HCl through which dry Cl2 is bubbled. Filter this solution which contains H2PdCl4 and H2PdCl6 and on evaporation it yields a residue of pure PdCl2. [Grube in Handbook of Preparative Inorganic Chemistry (Ed Brauer) Academic Press Vol II p 1582 1965, Mozingo Org Synth Coll Vol III 685 1955.]

Air & Water Reactions

Deliquescent. Water soluble.

General Description

Dark brown crystals.

Reactions

Palladium dichloride dissolves in HCl forming tetrachloropalladate ion,
PdCl2+2Cl¯→ [PdCl4]2¯
The complex ion catalyzes various types of organic reactions including oxidation of ethylene to acetaldehyde in aqueous solution (the Wacker Process):
PdCl42¯+ C2H4 + H2O → CH3CHO + Pd + 2HCl + 2Cl¯
Palladium dichloride forms polymeric carbonyl complexes when the dry chloride is heated in a stream of carbon monoxide charged with methane vapor. Such complexes include [PdCl2(CO)n] and [PdCl(CO)2]n. The reaction also occurs in aqueous phase resulting in decolorization of the solution.
When H2S is passed through palladium dichloride solution, it yields a brown-black precipitate of palladium monosulfide, PdS.
When heated with sulfur at 450 to 500°C, palladium dichloride forms palladium disulfide, PdS2, a grey-black crystalline compound, insoluble in strong acids but soluble in aqua regia, and which converts to monosulfide, PdS, on heating at 600°C.
When ammonia gas is passed through an aqueous solution of PdCl2, the product is tetrammine palladium(II) chloride, Pd(NH4)2Cl2. The same product also is obtained in dry state by passing ammonia gas over anhydrous PdCl2.

Production Methods

The palladium powder is added to the reactor containing hydrochloric acid, with stirring, passing the air, an oxidation reaction is performed, generating palladium chloride solution, the solution is purified, filtered, concentrated by evaporation, cooling and crystallization, centrifugal separation, and dried to obtain a palladium chloride finished products.
Pd+2HCl+0.5O2→PdCl2+H2O

Fire Hazard

Flash point data for Palladium chloride are not available. Palladium chloride is probably combustible.

Uses

Palladium dichloride is a starting material for preparing several palladium compounds. It also is used for detection of carbon monoxide. For such detection, a paper is soaked in very dilute solution of PdCl2 which is decolorized by CO, methane and other reducing substances. It also is used in toning and electroplating solutions and in photography for porcelain pictures.

Description

Palladium chloride is a commonly used precious metal catalysts, molecular formula is PaCl2, the appearance is brown-red needle-like crystals or powder, easily deliquescence, the relative density is 4.0 (18 ℃), melting point is 500 ℃ (decomposition), soluble in water, ethanol, acetone and hydrogen bromide. Decomposition in ammonia chloride, potassium iodide, ammonia solution, and precipitation of palladium.
[Uses]
(1)used as the analysis reagents, such as determination of trace palladium, mercury, thallium, iodine, etc.
(2) palladium test strips is used to test carbon monoxide.
(3) also used to search for cracks of buried underground gas pipeline cracks, study of agricultural plant resources, preparation of palladium catalyst, electroplating watch parts and photography, and so on.
[Preparation method] by melting palladium dichloride hydrate, make it lost part of chloride to get Palladium chlorine finished products.
the molecular structure of Palladium chloride
Figure 1 the molecular structure of Palladium chloride.
InChI:InChI=1/2ClH.2H2O.Pd/h2*1H;2*1H2;/q;;;;+2/p-2

7647-10-1 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (205885)  Palladium(II)chloride  ReagentPlus®, 99% 7647-10-1 205885-100G 36,024.30CNY Detail
Aldrich (205885)  Palladium(II)chloride  ReagentPlus®, 99% 7647-10-1 205885-25G 9,939.15CNY Detail
Aldrich (205885)  Palladium(II)chloride  ReagentPlus®, 99% 7647-10-1 205885-5G 2,453.49CNY Detail
Aldrich (205885)  Palladium(II)chloride  ReagentPlus®, 99% 7647-10-1 205885-1G 642.33CNY Detail
Aldrich (520659)  Palladium(II)chloride  ≥99.9% 7647-10-1 520659-100G 34,772.40CNY Detail
Aldrich (520659)  Palladium(II)chloride  ≥99.9% 7647-10-1 520659-25G 11,565.45CNY Detail
Aldrich (520659)  Palladium(II)chloride  ≥99.9% 7647-10-1 520659-5G 2,757.69CNY Detail
Aldrich (520659)  Palladium(II)chloride  ≥99.9% 7647-10-1 520659-1G 720.72CNY Detail
Aldrich (323373)  Palladium(II)chloride  99.999% 7647-10-1 323373-5G 4,986.54CNY Detail
Aldrich (323373)  Palladium(II)chloride  99.999% 7647-10-1 323373-1G 1,422.72CNY Detail
Alfa Aesar (12623)  Palladium(II) chloride, solution, Pd 9.0-11.0% w/w (cont. Pd)    7647-10-1 (c)5g 4381.0CNY Detail
Alfa Aesar (12623)  Palladium(II) chloride, solution, Pd 9.0-11.0% w/w (cont. Pd)    7647-10-1 (c)1g 1196.0CNY Detail

7647-10-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name palladium(II) chloride

1.2 Other means of identification

Product number -
Other names Palladium(II) Chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7647-10-1 SDS

7647-10-1Synthetic route

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

palladium(II) chloride
7647-10-1

palladium(II) chloride

N,N,N',N'-tetramethylethylenediamine palladium(II) chloride
14267-08-4

N,N,N',N'-tetramethylethylenediamine palladium(II) chloride

Conditions
ConditionsYield
In acetonitrile refluxing PdCl2-acetonitrile solution; cooling to 20°C; adding tmeda; analysis;90%
N,N,N'N'-tetramethyl-1,3-propanediamine
110-95-2

N,N,N'N'-tetramethyl-1,3-propanediamine

palladium(II) chloride
7647-10-1

palladium(II) chloride

dichlor(N,N,N',N'-tetramethyl-1,3-propanediamine)palladium(II)
21363-94-0

dichlor(N,N,N',N'-tetramethyl-1,3-propanediamine)palladium(II)

Conditions
ConditionsYield
In acetonitrile refluxing PdCl2-acetonitrile solution; cooling to 20°C; adding tmpda; analysis;90%
4-but-2-enyl-pyrrolidine-1,2-dicarboxylic acid 1-tert-butyl ester 2-methyl ester

4-but-2-enyl-pyrrolidine-1,2-dicarboxylic acid 1-tert-butyl ester 2-methyl ester

palladium(II) chloride
7647-10-1

palladium(II) chloride

4-(3-oxo-butyl)-pyrrolidine-1,2-dicarboxylic acid 1-tert-butyl ester 2-methyl ester

4-(3-oxo-butyl)-pyrrolidine-1,2-dicarboxylic acid 1-tert-butyl ester 2-methyl ester

Conditions
ConditionsYield
copper(I) chloride In water; N,N-dimethyl-formamide71%
copper(II) chloride dihydrate

copper(II) chloride dihydrate

4-allylazetidin-2-one
68485-52-9

4-allylazetidin-2-one

palladium(II) chloride
7647-10-1

palladium(II) chloride

sodium hydrogencarbonate
144-55-8

sodium hydrogencarbonate

4-(2-oxo-propyl)-azetidin-2-one
68485-90-5

4-(2-oxo-propyl)-azetidin-2-one

Conditions
ConditionsYield
mercury(II) diacetate In methanol; ethyl acetate70%
mercury(II) diacetate In methanol; ethyl acetate70%
4-bromo-1,3-benzenedicarboxylic acid dimethyl ester
28730-78-1

4-bromo-1,3-benzenedicarboxylic acid dimethyl ester

para-fluorostyrene
405-99-2

para-fluorostyrene

palladium(II) chloride
7647-10-1

palladium(II) chloride

A

methyl 4-[2-4-fluorophenyl)ethenyl]-3-methoxycarbonylbenzoate

methyl 4-[2-4-fluorophenyl)ethenyl]-3-methoxycarbonylbenzoate

B

(2S)-2-{2-(4-fluorophenethyl)-5-[1-(4-fluorophenyl)-2-(imidazol-1-yl)ethylaminomethyl]benzoylamino}-4-methylsulfanylbutyric acid

(2S)-2-{2-(4-fluorophenethyl)-5-[1-(4-fluorophenyl)-2-(imidazol-1-yl)ethylaminomethyl]benzoylamino}-4-methylsulfanylbutyric acid

Conditions
ConditionsYield
With tributyl-amine In dichloromethane; water
4-bromo-1,3-benzenedicarboxylic acid dimethyl ester
28730-78-1

4-bromo-1,3-benzenedicarboxylic acid dimethyl ester

para-fluorostyrene
405-99-2

para-fluorostyrene

palladium(II) chloride
7647-10-1

palladium(II) chloride

methyl 4-[2-(4-fluorophenyl)ethenyl]-3-methoxycarbonylbenzoate

methyl 4-[2-(4-fluorophenyl)ethenyl]-3-methoxycarbonylbenzoate

Conditions
ConditionsYield
With tributyl-amine In dichloromethane; water
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

palladium(II) chloride
7647-10-1

palladium(II) chloride

potassium carbonate
584-08-7

potassium carbonate

acrylic acid
79-10-7

acrylic acid

3-(4'-methoxyphenyl)propenoic acid
830-09-1

3-(4'-methoxyphenyl)propenoic acid

Conditions
ConditionsYield
In water
6-fluoro-3-nitroaniline
369-36-8

6-fluoro-3-nitroaniline

palladium(II) chloride
7647-10-1

palladium(II) chloride

2,4-Dinitrofluorobenzene
70-34-8

2,4-Dinitrofluorobenzene

4-Fluoro-3-nitroaniline
364-76-1

4-Fluoro-3-nitroaniline

Conditions
ConditionsYield
In palladium dichloride
cupric chloride

cupric chloride

C2 H5 O(C2 H4 O)18 C2 H5

C2 H5 O(C2 H4 O)18 C2 H5

1,11-dodecadiene
5876-87-9

1,11-dodecadiene

palladium(II) chloride
7647-10-1

palladium(II) chloride

A

1-dodecen-11-one
5009-33-6

1-dodecen-11-one

B

2,11-dodecadione
7029-09-6

2,11-dodecadione

Conditions
ConditionsYield
In water
cupric chloride

cupric chloride

C2 H5 O(C2 H4 O)18 CH3

C2 H5 O(C2 H4 O)18 CH3

6-methyl-1,5-heptadiene
7270-50-0

6-methyl-1,5-heptadiene

palladium(II) chloride
7647-10-1

palladium(II) chloride

6-Methyl-hept-5-en-2-on
110-93-0

6-Methyl-hept-5-en-2-on

Conditions
ConditionsYield
In water
furfural
98-01-1

furfural

palladium(II) chloride
7647-10-1

palladium(II) chloride

N-(3-chloro-4-(3-fluorobenzyloxy)phenyl)-6-iodoquinazolin-4-amine
231278-20-9

N-(3-chloro-4-(3-fluorobenzyloxy)phenyl)-6-iodoquinazolin-4-amine

5-(4-[3-chloro-4-(3-fluorobenzyloxy)-anilino]-6-quinazolinyl)-furan-2-carbaldehyde 4-methylbenzenesulfonate

5-(4-[3-chloro-4-(3-fluorobenzyloxy)-anilino]-6-quinazolinyl)-furan-2-carbaldehyde 4-methylbenzenesulfonate

Conditions
ConditionsYield
With N2; potassium acetate In 1,2-dimethoxyethane; water; N,N-dimethyl-formamide2.5 g (55%)
1,1'-bis(diphenylphosphino) ferrocene

1,1'-bis(diphenylphosphino) ferrocene

palladium(II) chloride
7647-10-1

palladium(II) chloride

2-(4-{2-[2-(4-bromophenyl)-5-methyloxazol-4-yl]ethoxy}phenoxy)-2-methylpropionic acid ethyl ester
328918-90-7

2-(4-{2-[2-(4-bromophenyl)-5-methyloxazol-4-yl]ethoxy}phenoxy)-2-methylpropionic acid ethyl ester

phenylboronic acid
98-80-6

phenylboronic acid

2-[4-(2-{2-[4-(4-Benzoyl-phenoxy)-phenyl]-5-methyl-oxazol-4-yl}-ethoxy)-phenoxy]-2-methyl-propionic Acid

2-[4-(2-{2-[4-(4-Benzoyl-phenoxy)-phenyl]-5-methyl-oxazol-4-yl}-ethoxy)-phenoxy]-2-methyl-propionic Acid

Conditions
ConditionsYield
With sodium hydroxide; K2CO3; potassium iodide In ethanol; methoxybenzene
1-Heptene
592-76-7

1-Heptene

palladium(II) chloride
7647-10-1

palladium(II) chloride

2C5H11CHCH2*2PdCl2={C5H11CHCH2PdCl2}2

2C5H11CHCH2*2PdCl2={C5H11CHCH2PdCl2}2

Conditions
ConditionsYield
In tetrahydrofuran Pd-compd. and 1-heptene (1.4 molar ratio) in THF stirred at room temp. for 30 min.;

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