79309-63-0Relevant articles and documents
Steroid Derived Mesoionic Gold and Silver Mono- and Polymetallic Carbenes
Frutos, María,De La Torre, María C.,Sierra, Miguel A.
, p. 11174 - 11185 (2015/12/17)
A two-step synthesis of gold mesoionic carbene complexes containing estrone moieties has been developed. The method uses the methylation of the triazole nucleus, followed by the treatment of the triazolium salt with Ag2O and transmetalation wit
Gold(i) "click" 1,2,3-triazolylidenes: Synthesis, self-assembly and catalysis
Kilpin, Kelly J.,Paul, Ursula S. D.,Lee, Ai-Lan,Crowley, James D.
supporting information; experimental part, p. 328 - 330 (2011/03/17)
Novel gold(i) "click" carbene(1,2,3-triazolylidene) complexes have been synthesised, characterised and exploited for the self-assembly of a metallomacrocycle and as precatalysts for gold(i)-catalysed reactions.
Deacylative oxidation strategy for the preparation of α- functionalized carbonyls
Brodsky, Benjamin H.,Du Bois
, p. 2619 - 2621 (2007/10/03)
(Matrix Presented) α-Alkoxylation and amination of carbonyl derivatives is made possible through a unique deacylative coupling reaction that proceeds via in situ Rh-carbene formation and subsequent heteroatom-H (X-H) insertion. Reactions perform optimally
