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79606-43-2

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  • Benzamide, 4-methoxy-N,N-bis(1-methylethyl)-

    Cas No: 79606-43-2

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79606-43-2 Usage

General Description

N,N-Diisopropyl-4-methoxybenzamide is a chemical compound that belongs to the class of benzamides. It is a white solid that is used as a pharmaceutical intermediate and as a building block in organic synthesis. N,N-DIISOPROPYL-4-METHOXYBENZAMIDE is commonly used in the production of various pharmaceuticals and is also utilized as an intermediate in the synthesis of other organic compounds. It has the molecular formula C13H21NO2 and a molecular weight of 223.31 g/mol. N,N-Diisopropyl-4-methoxybenzamide is known to have mild to moderate acute toxicity and should be handled and used with appropriate safety precautions.

Check Digit Verification of cas no

The CAS Registry Mumber 79606-43-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,9,6,0 and 6 respectively; the second part has 2 digits, 4 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 79606-43:
(7*7)+(6*9)+(5*6)+(4*0)+(3*6)+(2*4)+(1*3)=162
162 % 10 = 2
So 79606-43-2 is a valid CAS Registry Number.
InChI:InChI=1/C14H21NO2/c1-10(2)15(11(3)4)14(16)12-6-8-13(17-5)9-7-12/h6-11H,1-5H3

79606-43-2 Well-known Company Product Price

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  • Alfa Aesar

  • (H59383)  N,N-Diisopropyl-4-methoxybenzamide, 97%   

  • 79606-43-2

  • 250mg

  • 1260.0CNY

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  • Alfa Aesar

  • (H59383)  N,N-Diisopropyl-4-methoxybenzamide, 97%   

  • 79606-43-2

  • 1g

  • 4032.0CNY

  • Detail

79606-43-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-methoxy-N,N-di(propan-2-yl)benzamide

1.2 Other means of identification

Product number -
Other names N,N-DIISOPROPYL-4-METHOXYBENZAMIDE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:79606-43-2 SDS

79606-43-2Relevant articles and documents

3-(3'-hydroxybutyl) isobenzofuran-1(3H)-ketone derivative as well as composition, preparation method and application thereof

-

Paragraph 0071-0072; 0085; 0088; 0091; 0096; 0098, (2021/05/15)

The invention belongs to the field of medicines, and particularly relates to a 3-(3-hydroxybutyl) isobenzofuran-1(3H)-ketone derivative as well as a composition, a preparation method and application thereof, and the derivative is a compound with a structu

HMF and furfural: Promising platform molecules in rhodium-catalyzed carbonylation reactions for the synthesis of furfuryl esters and tertiary amides

Qi, Xinxin,Zhou, Rong,Ai, Han-Jun,Wu, Xiao-Feng

, p. 215 - 221 (2019/11/25)

A biomass involved rhodium-catalyzed carbonylative synthesis of furfuryl esters and tertiary amides has been developed. 5-Hydroxymethylfurfural (HMF) was used as both substrate and CO surrogate for the first time in a carbonylation reaction, and both alkyl and aryl iodides were tolerated well to afford the desired furfuryl esters in moderate to good yields. In addition, furfural was also utilized as a CO source for the synthesis of tertiary amides. A variety of tertiary amides were obtained in moderate to excellent yields with good functional groups compatibility. Notably, tertiary amines were used as the amine source through a C[sbnd]N bond cleavage pathway in the absence of additional oxidant.

Chemoselective Reduction of Sterically Demanding N,N-Diisopropylamides to Aldehydes

Xiao, Peihong,Tang, Zhixing,Wang, Kai,Chen, Hua,Guo, Qianyou,Chu, Yang,Gao, Lu,Song, Zhenlei

, p. 1687 - 1700 (2018/02/23)

A sequential one-pot process for chemoselectively reducing sterically demanding N,N-diisopropylamides to aldehydes has been developed. In this reaction, amides are activated with EtOTf to form imidates, which are reduced with LiAlH(OR)3 [R = t-Bu, Et] to give aldehydes by hydrolysis of the resulting hemiaminals. The non-nucleophilic base 2,6-DTBMP remarkably improves reaction efficiency. The combination of EtOTf/2,6-DTBMP and LiAlH(O-t-Bu)3 was found to be optimal for reducing alkyl, alkenyl, alkynyl, and 2-monosubstituted aryl N,N-diisopropylamides. In contrast, EtOTf and LiAlH(OEt)3 in the absence of base were found to be optimal for reducing extremely sterically demanding 2,6-disubstituted N,N-diisopropylbenzamides. The reaction tolerates various reducible functional groups, including aldehyde and ketone. 1H NMR studies confirmed the formation of imidates stable in water. The synthetic usefulness of this methodology was demonstrated with N,N-diisopropylamide-directed ortho-metalation and C-H bond activation.

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