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82398-30-9

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  • Benzenemethanamine,a-methyl-N-[(1R)-1-phenylethyl]-,hydrochloride (1:1), (aR)- Manufacturer/High quality/Best price/In stock

    Cas No: 82398-30-9

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82398-30-9 Usage

Chemical Properties

white to light yellow crystal powde

Uses

(αR)-α-Methyl-N-[(1R)-1-phenylethyl]benzenemethanamine Hydrochloride is used in the synthesis of the highly potent anti-metastatic prostacyclin analogue Cicaprost (C432750). Also used in the synthesis of a key A-Ring intermediate in the preparation of 1α-fluoro vitamin D3 analogues.

Check Digit Verification of cas no

The CAS Registry Mumber 82398-30-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,2,3,9 and 8 respectively; the second part has 2 digits, 3 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 82398-30:
(7*8)+(6*2)+(5*3)+(4*9)+(3*8)+(2*3)+(1*0)=149
149 % 10 = 9
So 82398-30-9 is a valid CAS Registry Number.
InChI:InChI=1/C16H19N/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16/h3-14,17H,1-2H3/p+1/t13-,14-/m1/s1

82398-30-9 Well-known Company Product Price

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  • Aldrich

  • (461520)  (+)-Bis[(R)-1-phenylethyl]amine hydrochloride  97%

  • 82398-30-9

  • 461520-5G

  • 1,937.52CNY

  • Detail

82398-30-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name (R,R)-(+)-Bis(alpha-methylbenzyl)amine Hydrochloride

1.2 Other means of identification

Product number -
Other names (R,R)-(+)-BIS(α-METHYLBENZYL)AMINE HYDROCHLORIDE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:82398-30-9 SDS

82398-30-9Relevant articles and documents

Metal-free transfer hydrogenation catalysis by B(C6F 5)3

Farrell, Jeffrey M.,Heiden, Zachariah M.,Stephan, Douglas W.

body text, p. 4497 - 4500 (2011/11/04)

The activation of amines by B(C6F5)3 is shown to effect the catalytic racemization of a chiral amine. Extending this strategy to a bimolecular process, catalytic transfer hydrogenation of imines, enamines, and N-heterocycles is demonstrated using iPr2NH as the source of hydrogen and a catalytic amount of the Lewis acid B(C 6F5)3.

Development of new HPLC chiral stationary phases based on native and derivatized cyclofructans

Sun, Ping,Wang, Chunlei,Breitbach, Zachary S.,Zhang, Ying,Armstrong, Daniel W.

experimental part, p. 10215 - 10226 (2010/05/01)

An unusual class of chiral selectors, cyclofructans, is introduced for the first time as bonded chiral stationary phases. Compared to native cyclofructans (CFs), which have rather limited capabilities as chiral selectors, aliphatic-and aromatic-functionalized CF6s possess unique and very different enantiomeric selectivities. Indeed, they are shown to separate a very broad range of racemic compounds. In particular, aliphatic-derivatized CF6s with a low substitution degree baseline separate all tested chiral primary amines. It appears that partial derivatization on the CF6 molecule disrupts the molecular internal hydrogen bonding, thereby making the core of the molecule more accessible. In contrast, highly aromaticfunctionalized CF6 stationary phases lose most of the enantioselective capabilities toward primary amines, however they gain broad selectivity for most other types of analytes. This class of stationary phases also demonstrates high "loadability" and therefore has great potential for preparative separations. The variations in enantiomeric selectivity often can be correlated with distinct structural features of the selector. The separations occur predominantly in the presence of organic solvents.

Stereospecific Symthesis of N-(1-Phenylethyl)-2,4,5-triphenyloxazolidines

Alcaide, Benito,Lopez-Mardomingo, Carmen,Perez-Ossorio, Rafael,Plumet, Joaquin

, p. 45 - 48 (2007/10/02)

Treatment of the diastereoisomeric N-(1-phenylethyl)-1,2-diphenyl-2-aminoethanols with benzaldehyde yields stereospecifically N-(1-phenylethyl)-2,4,5-triphenyloxazolidines with four chiral centers.The cofigurations of these oxazolidines are established th

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