83887-62-1

Basic information

• Product Name: 4-benzoylphenyl methanesulfonate
• Synonyms: 4-benzoylphenyl methanesulfonate
• CAS NO: 83887-62-1
• Molecular Formula: C₁₄H₁₂O₄S
• Molecular Weight: 276.30768
• Mol File: 83887-62-1.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-benzoylphenyl methanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-benzoylphenyl methanesulfonate(83887-62-1)
• EPA Substance Registry System: 4-benzoylphenyl methanesulfonate(83887-62-1)

Safety Data

• Hazardous Substances Data: 83887-62-1(Hazardous Substances Data)

Upstream product

• 75-75-2 methanesulfonic acid 
• 93-99-2 benzoic acid phenyl ester 
• 16513-74-9 <4-(Benzoyloxy)phenyl>phenylketon 
• 124-63-0 methanesulfonyl chloride 
• 1137-42-4 4-Hydroxybenzophenone 
• 16156-59-5 phenyl methanesulfonate 
• 36967-85-8 benzoyl triflate 
• 65-85-0 benzoic acid 
• 532-32-1 sodium benzoate 

Downstream Products

• 2128-93-0 biphenyl-4-yl-phenyl-methanone 
• 1067883-66-2 (2',6'-dimethylbiphenyl-4-yl)phenyl-methanone 
• 1314564-61-8 (4-((benzyloxy)methyl)phenyl)(phenyl)methanone 
• 1503-49-7 p-cyanobenzophenone 
• 103384-72-1 diethyl (4-benzoylphenyl)phosphonate 
• 1160237-62-6 tert-butyl 4-benzoylbenzylcarbamate 
• 269410-03-9 phenyl-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methanone 
• 63283-56-7 4-benzoyl-4'-methylbiphenyl 
• 1235553-94-2 ((4-(naphthalene-2-yl)phenyl)phenyl)methanone 
• 1009026-35-0 phenyl[4'-(trifluoromethyl)[1,1'-biphenyl]-4-yl]methanone 

Relevant articles and documents

Decarboxylation with Carbon Monoxide: The Direct Conversion of Carboxylic Acids into Potent Acid Triflate Electrophiles

We report a new strategy for the conversion of carboxylic acids into potent acid triflate electrophiles. The reaction involves oxidative carbonylation of carboxylic acids with I2 in the presence of AgOTf, and is postulated to proceed via acyl hypoiodites that react with CO to form acid triflates. Coupling this chemistry with subsequent trapping with arenes offers a mild, room temperature approach to generate ketones directly from broadly available carboxylic acids without the use of corrosive and reactive Lewis or Bronsted acid additives, and instead from compounds that are readily available, stable, and functional group compatible.

Palladium-catalyzed borylation of aryl mesylates and tosylates and their applications in one-pot sequential suzuki-miyaura biaryl synthesis

Top of the one-pots! The first palladium-catalyzed borylation of aryl tosylates and mesylates is described. The reaction conditions are mild and provide excellent functional-group compatibility (e.g., R=CN, CHO, COOMe, C(O)R, NH2, or NH-indole; see scheme). Pd/MeO-CM-phos allows one-pot sequential reactions in the preparation of unsymmetrical biaryls. Copyright

A mild and efficient palladium-catalyzed cyanation of aryl mesylates in water or tBuOH/water

Cool and compatible: Aryl mesylates and tosylates underwent palladium-catalyzed cyanation under mild, aqueous conditions at 65-80°C (see scheme). In many cases, water could be used as the reaction medium without a cosolvent, and a variety of substituents R, such as keto, aldehyde, ester, free amine, and nitrile groups, remained intact during the transformation. Cy=cyclohexyl, Ms=methanesulfonyl, Ts=p-toluenesulfonyl.