86535-40-2

Upstream product

• 27983-42-2 5-carboethoxypentanal 
• 65-85-0 benzoic acid 
• 114826-55-0 Benzoic acid (R)-4-ethoxycarbonyl-1-hydroxymethyl-butyl ester 
• 114826-54-9 Benzoic acid (Z)-(R)-1-benzyloxymethyl-4-ethoxycarbonyl-but-3-enyl ester 
• 114826-53-8 Benzoic acid (R)-1-benzyloxymethyl-3-oxo-propyl ester 
• 114826-51-6 (R)-2-benzoyloxy-1-benzyloxy-3-butene 
• 114826-52-7 Benzoic acid (R)-1-benzyloxymethyl-3-hydroxy-propyl ester 
• 98-88-4 benzoyl chloride 
• 92007-81-3 Benzoic acid (R)-1-((S)-1,2-dihydroxy-ethyl)-4-ethoxycarbonyl-butyl ester 

Downstream Products

• 82493-59-2 ethyl 5(S)-(benzoyloxy)-12(R)-<(tert-butyldiphenylsilyl)oxy>-6(Z),8(E),10(E),14(Z)-icosatetraenoate 
• 82493-59-2 Benzoic acid (2Z,4E,6E,10Z)-(1S,8S)-8-(tert-butyl-diphenyl-silanyloxy)-1-(3-ethoxycarbonyl-propyl)-hexadeca-2,4,6,10-tetraenyl ester 
• 83709-73-3 12-epi-leukotriene B4 
• 71160-24-2 Leukotriene B 
• 70578-51-7 (6Z,8E,10E,14Z)-(5S,12R)-5,12-Dihydroxy-icosa-6,8,10,14-tetraenoic acid 
• 82493-60-5 Benzoic acid (2Z,4E,6E,10Z)-(1S,8R)-1-(3-ethoxycarbonyl-propyl)-8-hydroxy-hexadeca-2,4,6,10-tetraenyl ester 
• 137522-23-7 Benzoic acid (2E,4E,6E,10Z)-(1S,8R)-8-(tert-butyl-dimethyl-silanyloxy)-1-(3-ethoxycarbonyl-propyl)-hexadeca-2,4,6,10-tetraenyl ester 
• 137522-23-7 Benzoic acid (2Z,4E,6E,10Z)-(1R,8R)-8-(tert-butyl-dimethyl-silanyloxy)-1-(3-ethoxycarbonyl-propyl)-hexadeca-2,4,6,10-tetraenyl ester 

Relevant academic research and scientific papers

METHOD FOR PRODUCING ALPHA-ACYLOXYCARBONYL COMPOUND AND NOVEL ALPHA-ACYLOXYCARBONYL COMPOUND

A method for producing an α-acyloxycarbonyl compound of the present invention includes performing an intermolecular reaction between a carboxylic acid and a carbonyl compound selected from the group consisting of ketones, aldehydes, and esters, which have

In situ generated (Hypo)iodite catalysts for the direct α-oxyacylation of carbonyl compounds with carboxylic acids

It′s the iodine: The intra- and intermolecular title reaction is catalyzed by an in situ generated ammonium (hypo)iodite species. Either H 2O2 or tert-butyl hydroperoxide (TBHP) can be used as an environmentally benign oxidant and a wide range of substrates react to give the corresponding α-acyloxycarbonyl compounds in good to excellent yields.

New method for synthesizing the intermediates to 5-HETE from yeast-mediated reduction products by employing Baeyer-Villiger oxidation with complete retention of enantiomeric excess.

(R) and (S)-Aldehydes 2, which are intermediates for the synthesis of (5R) and (5S)-HETE, were respectively synthesized from the yeast-mediated reductive products, hydroxy ester 3 and cis-lactone 4, through Baeyer-Villiger oxidation with complete retention of enantiomeric excess.

SYNTHESIS OF (R)-1-BENZYLOXY-3-BUTEN-2-OL- A POTENTIAL CHIRAL SYNTHON FROM L-(+)-TARTARIC ACID: ITS APPLICATIONS IN NATURAL PRODUCT SYNTHESES

A practical synthesis of (R)-3-butene-1,2-diol derivatives from (R,R)-tartaric acid and their applications for the syntheses of (R)-ethyl-5-benzoyloxy-5-formyl pentanoate (2), a useful synthon for the preparation of arachidonic acid metabolites and (R)-γ-caprolactone (3), a pheromone of Trogoderma species, are described.

STEREOSPECIFIC SYNTHESIS OF LEUKOTRIENE B4 (LTB4)

A stereospecific and chirally economical synthesis of LTB4 starting from 2-deoxy-D-ribose is reported as part of a comprehensive and efficient approach to the Leukotrienes (A, B, C, D, E).The process includes a novel approach to chiral dienic synthons.