86770-02-7

Upstream product

• 86769-97-3 (E)-N-methyl-2-styrylbenzamide 
• 5342-91-6 2-methylisoindolin-1-one 
• 100-39-0 benzyl bromide 
• 67-64-1 acetone 
• 566151-96-0 3-benzyl-2-methyl-3-phenylsulfanyl-2,3-dihydro-isoindol-1-one 
• 29879-69-4 3-hydroxy-2-methyl-isoindolin-1-one 
• 408325-03-1 2-methyl-3-phenylsulfanyl-2,3-dihydro-isoindol-1-one 
• 122-78-1 phenylacetaldehyde 
• 907174-66-7 C₁₅H₁₁ClO 
• 60901-21-5 o-styrylbenzoic acid 
• 100-42-5 styrene 
• 610-97-9 o-iodo-methyl-benzoic acid 
• 122860-79-1 Methyl-[2-phenyl-eth-(Z)-ylidene]-amine 
• 550-44-7 N-methylphthalimide 

Relevant academic research and scientific papers

Intramolecular Hydroamidation of ortho-Vinyl Benzamides Promoted by Potassium tert-Butoxide/N,N-Dimethylformamide

An intramolecular hydroamidation of ortho-vinyl benzamides had been developed. The reaction was promoted efficiently by potassium tert-butoxide and N,N-dimethylformamide without the need for strong oxidants or transition-metal catalysts. A series of dihyd

Novel chemoselective desulfurization of γ-phenylthio-substituted aromatic lactams: Application to the synthesis of isoindolobenzazepine alkaloid, lennoxamine

Treatment of a variety of γ-phenylthio-substituted aromatic lactams with lithium aluminum hydride in the presence of cuprous iodide led to novel chemoselective desulfurization reactions to afford the corresponding substituted aromatic lactams without givi

A new entry for the preparation of substituted aromatic carbonyl compounds mediated by Samarium(II) iodide

A new route to substituted aromatic lactones and lactams via SMI2-promoted desulfurization is described. Direct replacement of the phenylthio substituent by hydroxyalkylated groups featuring the novel accessible process for the construction of continuous quaternary carbon centers could be accomplished when the same type of reactions was undertaken with carbonyl compounds in the presence of SmI2.

Regiochemistry in aryl radical cyclisations (5-exo versus 6-endo) of N-vinylic 2-iodobenzamides

Bu3SnH-mediated aryl radical cyclisations of a range of N-vinylic 2-iodobenzamides 10 were examined. The enamides 10a-d gave exclusively the 5-exo cyclisation products 11a-d, whereas the enamides 10e,f having a phenyl substituent on the vinylic carbon ato

LDA-induced metalation of isoindolinones. An efficient route to 3- substituted isoindoline derivatives

3-Substituted isoindolines have been efficiently prepared by sequential lithiation and reduction of isoindolinones.

BASE-CATALYZED CYCLISATION OF N-ALKYL-(E)-STILBENE-2-CARBOXAMIDES

When the N-substituent is a not-hindered alkyl group, the title compounds (1) cyclise to the corresponding N-alkyl-3-benzylphtalimides (2).