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88-43-7

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88-43-7 Usage

Flammability and Explosibility

Notclassified

Check Digit Verification of cas no

The CAS Registry Mumber 88-43-7 includes 5 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 2 digits, 8 and 8 respectively; the second part has 2 digits, 4 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 88-43:
(4*8)+(3*8)+(2*4)+(1*3)=67
67 % 10 = 7
So 88-43-7 is a valid CAS Registry Number.
InChI:InChI=1/C6H6ClNO3S/c7-5-2-1-4(8)3-6(5)12(9,10)11/h1-3H,8H2,(H,9,10,11)

88-43-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 5-amino-2-chlorobenzenesulfonic acid

1.2 Other means of identification

Product number -
Other names 6-chloro-3-aminobenzenesulfonic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:88-43-7 SDS

88-43-7Synthetic route

2-chloro-5-nitro-benzenesulfonic acid
96-73-1

2-chloro-5-nitro-benzenesulfonic acid

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

Conditions
ConditionsYield
With barium dihydroxide; iron(II) sulfate
With hydrogenchloride; tin
With titanium(III) chloride
4-chloro-aniline
106-47-8

4-chloro-aniline

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

Conditions
ConditionsYield
With sulfuric acid
With sulfuric acid
4-chloro-aniline
106-47-8

4-chloro-aniline

A

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

B

2-amino-5-chlorobenzenesulfonic acid
133-74-4

2-amino-5-chlorobenzenesulfonic acid

Conditions
ConditionsYield
With sulfuric acid
N-(4-chlorophenyl)acetamide
539-03-7

N-(4-chlorophenyl)acetamide

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

Conditions
ConditionsYield
With sulfuric acid at 145℃;
sulfuric acid
7664-93-9

sulfuric acid

4-chloro-aniline
106-47-8

4-chloro-aniline

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

sulfuric acid
7664-93-9

sulfuric acid

N-(4-chlorophenyl)acetamide
539-03-7

N-(4-chlorophenyl)acetamide

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

Conditions
ConditionsYield
at 150℃;
2-chloro-5-nitro-benzenesulfonic acid
96-73-1

2-chloro-5-nitro-benzenesulfonic acid

Fe(OH)2

Fe(OH)2

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

hydrogenchloride
7647-01-0

hydrogenchloride

2-chloro-5-nitro-benzenesulfonic acid
96-73-1

2-chloro-5-nitro-benzenesulfonic acid

tin

tin

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

C16H16N2O

C16H16N2O

C22H20ClN3O3S

C22H20ClN3O3S

Conditions
ConditionsYield
With hydrogenchloride In methanol; water at 70℃;86%
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

2,5-diaminobenzenesulfonic acid
88-45-9

2,5-diaminobenzenesulfonic acid

Conditions
ConditionsYield
With copper salt; ammonia unter Druck;
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

5-bromo-2-chloro-benzenesulfonic acid

5-bromo-2-chloro-benzenesulfonic acid

Conditions
ConditionsYield
durch Austausch von NH2 gegen Br;
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

5-amino-2-chloro-benzenesulfonyl chloride
133121-38-7

5-amino-2-chloro-benzenesulfonyl chloride

Conditions
ConditionsYield
With chlorosulphuric acid
With chlorosulphuric acid
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

2-chloro-5-sulfanilylamino-benzenesulfonic acid

2-chloro-5-sulfanilylamino-benzenesulfonic acid

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

4-chloro-3-sulfo-benzenediazonium-betaine

4-chloro-3-sulfo-benzenediazonium-betaine

Conditions
ConditionsYield
Diazotization;
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

3-Chloro-5-sulfo-benzenediazonium; chloride

3-Chloro-5-sulfo-benzenediazonium; chloride

Conditions
ConditionsYield
With hydrogenchloride; sodium nitrite In water at 0 - 5℃;
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

2-amino-5-chloro-benzene-1,4-disulfonic acid diamide
1019-50-7

2-amino-5-chloro-benzene-1,4-disulfonic acid diamide

Conditions
ConditionsYield
(i) ClSO3H, NaCl, (heating), (ii) aq. NH3; Multistep reaction;
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

ammonia
7664-41-7

ammonia

copper

copper

2,5-diaminobenzenesulfonic acid
88-45-9

2,5-diaminobenzenesulfonic acid

Conditions
ConditionsYield
unter Druck;
4-methyleneoxetan-2-one
674-82-8

4-methyleneoxetan-2-one

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

6-chloro-3-acetoacetylamino-benzene-sulfonic acid-(1)

6-chloro-3-acetoacetylamino-benzene-sulfonic acid-(1)

thiophosgene
463-71-8

thiophosgene

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

6-chloro-3-isothiocyanato-benzene-sulfonic acid-(1)

6-chloro-3-isothiocyanato-benzene-sulfonic acid-(1)

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

water
7732-18-5

water

bromine
7726-95-6

bromine

compound C6H4Br2ClNO3S

compound C6H4Br2ClNO3S

β-oxynaphthanilic acid

β-oxynaphthanilic acid

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

GENERIC INORGANIC CATION; 5-[N'-(3-carboxy-2-oxo-2H-naphthalen-1-ylidene)-hydrazino]-2-chloro-benzenesulfonate

GENERIC INORGANIC CATION; 5-[N'-(3-carboxy-2-oxo-2H-naphthalen-1-ylidene)-hydrazino]-2-chloro-benzenesulfonate

Conditions
ConditionsYield
Stage #1: 4-chloroaniline-3-sulfonic acid With hydrogenchloride; sodium carbonate; sodium nitrite at 5℃;
Stage #2: β-oxynaphthanilic acid for 1h; cooling;
Stage #3: With calcium chloride
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

2-Chloro-5-(4,6-diamino-2-ethylsulfanyl-pyrimidin-5-ylazo)-benzenesulfonic acid
105548-05-8

2-Chloro-5-(4,6-diamino-2-ethylsulfanyl-pyrimidin-5-ylazo)-benzenesulfonic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium nitrite, hydrochloric acid / H2O / 0 - 5 °C
View Scheme
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

5-(5-Amino-3-methyl-1-phenyl-1H-pyrazol-4-ylazo)-2-chloro-benzenesulfonic acid
105547-65-7

5-(5-Amino-3-methyl-1-phenyl-1H-pyrazol-4-ylazo)-2-chloro-benzenesulfonic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium nitrite, hydrochloric acid / H2O / 0 - 5 °C
View Scheme
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

5-(4-Amino-2-diethylamino-6-methyl-pyrimidin-5-ylazo)-2-chloro-benzenesulfonic acid
105547-86-2

5-(4-Amino-2-diethylamino-6-methyl-pyrimidin-5-ylazo)-2-chloro-benzenesulfonic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium nitrite, hydrochloric acid / H2O / 0 - 5 °C
View Scheme
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

5-(2-Acetylamino-4-diethylamino-phenylazo)-2-chloro-benzenesulfonic acid
105548-24-1

5-(2-Acetylamino-4-diethylamino-phenylazo)-2-chloro-benzenesulfonic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium nitrite, hydrochloric acid / H2O / 0 - 5 °C
View Scheme
4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

2-Chloro-5-[1-(4-chloro-phenyl)-5-hydroxy-3-methyl-1H-pyrazol-4-ylazo]-benzenesulfonic acid

2-Chloro-5-[1-(4-chloro-phenyl)-5-hydroxy-3-methyl-1H-pyrazol-4-ylazo]-benzenesulfonic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium nitrite, hydrochloric acid / H2O / 0 - 5 °C
View Scheme
N-[7-(chlorosulfonyl)-5-hydroxy(2-naphthyl)]{[7-(chlorosulfonyl)-5-hydroxy(2-naphthyl)]amino}carboxamide
309933-11-7

N-[7-(chlorosulfonyl)-5-hydroxy(2-naphthyl)]{[7-(chlorosulfonyl)-5-hydroxy(2-naphthyl)]amino}carboxamide

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

4-hydroxy-7-{[(5-hydroxy-7-sulfo-(2-naphthyl))amino]carbonylamino}naphthalene-2-sulfonic acid

4-hydroxy-7-{[(5-hydroxy-7-sulfo-(2-naphthyl))amino]carbonylamino}naphthalene-2-sulfonic acid

Conditions
ConditionsYield
With pyridine In tetrahydrofuran
2-(3-sulfopropoxy)-5-chloroaniline
1220101-73-4

2-(3-sulfopropoxy)-5-chloroaniline

4-chloroaniline-3-sulfonic acid
88-43-7

4-chloroaniline-3-sulfonic acid

C15H15Cl2N3O7S2
1263864-38-5

C15H15Cl2N3O7S2

Conditions
ConditionsYield
Stage #1: 4-chloroaniline-3-sulfonic acid With hydrogenchloride; sodium hydroxide; sodium nitrite In water at 0 - 10℃; for 1.5h;
Stage #2: 2-(3-sulfopropoxy)-5-chloroaniline With sodium hydroxide In water
Stage #1: 4-chloroaniline-3-sulfonic acid With hydrogenchloride; sodium hydroxide; sodium nitrite In water at 10℃; for 1.5h; pH=6;
Stage #2: 2-(3-sulfopropoxy)-5-chloroaniline With sodium hydrogensulfite; sodium hydroxide In water pH=7; Further stages;
Stage #1: 4-chloroaniline-3-sulfonic acid With hydrogenchloride; sodium nitrite In water at 0 - 10℃; for 1h; pH=2 - 4;
Stage #2: 2-(3-sulfopropoxy)-5-chloroaniline With sodium hydrogensulfite; sodium hydroxide In water at 0 - 15℃;
Stage #1: 4-chloroaniline-3-sulfonic acid With sodium hydroxide In water pH=6;
Stage #2: With hydrogenchloride; sodium nitrite In water at 0 - 10℃; for 1.5h;
Stage #3: 2-(3-sulfopropoxy)-5-chloroaniline Further stages;

88-43-7Relevant articles and documents

Process for the preparation of aminobenzenesulfonic acids

-

, (2008/06/13)

There is disclosed a process for the preparation of compounds of formula STR1 wherein the symbols are as defined in claim 1, which process comprises dissolving a compound of formula STR2 in sulfuric acid, adding this solution to oleum and reacting the mixture in the temperature range from 10° to 80° C. until a sulfo group has been completely introduced, and, in an optional further step, subjecting the reaction mixture to further reaction in the temperature range from 100° to 200° C. to introduce a second sulfo group. The compounds of formula (1) obtainable by this process are useful intermediates for the synthesis of dyes and are particularly suitable diazo components for the synthesis of azo dyes.

Alkanol substituted disazo orange dye for nylon

-

, (2008/06/13)

The specification describes a new group of alkanol substituted disazo compounds that are useful in dyeing polyamide textile fibers in orange hues. The new compounds are compatible with several acid blue dyes and several acid red dyes that are commercially important as dyes for nylon. The new compounds are particularly well suited for use as the "yellow" component in trichromatic systems for dying polyamide carpeting and other textiles. The new compounds are relatively inexpensive to make and have outstanding application and fastness properties. Other aspects of the specification are concerned with a method of making the new compounds and with a method of dyeing polyamides with said compounds and to the novel dyed polyamides resulting from the use of the new group of compounds as dyes.

Reactive dyestuffs comprising a triazine moiety and a vinylsulfonyl moiety both being linked by a substituted alkylene bridge member

-

, (2008/06/13)

A reactive dye of the formula STR1 in which: F is a radical selected from the group consisting of metal-free or metal-containing monoazo or disazo dyes containing at least one --SO3 H group, anthraquinone dyes, sulfophthalocyanine dyes, formazan dyes, phenazine dyes, oxazine dyes and nitroaryl dyes, R is hydrogen, C1 -C4 alkyl which is unsubstituted or substituted with --COOH or --SO3 H, cyanoethyl, or hydroxyethyl, X is fluorine, chlorine, bromine, --SO3 H, phenylsulfonyl or C1 -C4 -alkylsulfonyl, p is 1 or 2 and A is a radical of the formula STR2 in which: Y is chlorine, bromine, fluorine, --OH, --OSO3 H, --O-acyl, --CN, --COOH, --COO--C1 -C4 -alkyl, --CONH2 or --SO2 --Z, the group designated "alk" is a straight or branched polymethylene radical having 2 to 6 carbon atoms, V is STR3 hydrogen or C1 -C4 -alkyl which is unsubstituted or substituted by C1 -C2 -alkoxy, carboxyl, sulfo, halogen or hydroxy, Z is β-halogenoethyl, vinyl or β-acetoxyethyl, or A is a radical of the formulae STR4 in all of which R' is C1-6 -alkyl or hydrogen, Z is as defined above, o is 0 to 6, and m is 2 to 6.

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