929554-11-0

Upstream product

• 111466-55-8 ((2S,3S)-3-(2-(benzyloxy)ethyl)oxiran-2-yl)methanol 
• 89923-31-9 (E)-5-(benzyloxy)pent-2-en-1-ol 
• 22273-79-6 5-benzyloxy-2-pentyn-1-ol 
• 22273-77-4 ((but-3-yn-1-yloxy)methyl)benzene 
• 100-39-0 benzyl bromide 

Downstream Products

• 1000866-32-9 (2S,6R)-8-hydroxy-6-methoxyoctan-2-yl (3,5-dimethoxyphenyl)acetate 
• 1000866-33-0 (1S,5R)-6-carboxy-5-methoxy-1-methylhexyl 3,5-dimethoxybenzeneacetate 
• 90319-47-4 (3S)-5-(benzyloxy)pent-1-yn-3-ol 
• 172516-17-5 (S)-3-((tert-butyldiphenylsilyl)oxy)pent-4-enal 
• 929554-00-7 (1R)-1-methyl-5-hexenyl (3S)-3-tert-butyldiphenylsilyloxy-4-pentenoate 
• 929554-13-2 (3S)-3-tert-butyldiphenylsilyloxy-5-benzyloxy-1-pentene 
• 929554-04-1 (3S)-3-(tert-butyldiphenylsilyloxy)pent-4-enoic acid 
• 929554-15-4 (3S)-3-tert-butyldiphenylsilyloxy-5-hydroxy-1-pentene 
• 117661-29-7 (3S)-3-hydroxy-5-benzyloxy-1-pentene 

Relevant academic research and scientific papers

An efficient stereoselective total synthesis of 11β-methoxycurvularin

A very short and efficient stereoselective total synthesis of a macrocyclic ketone, 11β-methoxycurvularin was achieved by employing the Sharpless asymmetric epoxidation, formation of propargyl alcohols from an epoxy-chloride, and intramolecular Friedel-Cr

Stereoselective synthesis of (+)-diplodialides-B, C and a formal synthesis of (+)-diplodialide-A by ring-closing metathesis approach

Stereoselective synthesis of diplodialides-B and C and the formal synthesis of diplodialide-A are reported. A combination of Jacobsen's hydrolytic kinetic resolution and Sharpless epoxidation is used for the creation of two stereogenic centers, while a ring-closing metathesis strategy was used for the construction of the lactone ring.