940-38-5

Basic information

• Product Name: Carbamic azide, phenyl-
• CAS NO: 940-38-5
• Molecular Formula: C7H6N4O
• Molecular Weight: 162.151
• Mol File: 940-38-5.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Carbamic azide, phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic azide, phenyl-(940-38-5)
• EPA Substance Registry System: Carbamic azide, phenyl-(940-38-5)

Safety Data

• Hazardous Substances Data: 940-38-5(Hazardous Substances Data)

Upstream product

• 613-90-1 benzoyl cyanide 
• 5441-14-5 4-phenylsemicarbazide hydrochloride 
• 103-71-9 phenyl isocyanate 
• 93-58-3 benzoic acid methyl ester 
• 93-89-0 benzoic acid ethyl ester 
• 100-52-7 benzaldehyde 
• 23316-67-8 2,3,5-tri-O-benzoyl-β-D-ribofuranosyl-1-carbonitrile 
• 7782-77-6 cis-nitrous acid 
• 537-47-3 4-phenyl-semicarbazide 
• 100-51-6 benzyl alcohol 
• 67-56-1 methanol 
• 98-88-4 benzoyl chloride 
• 100-46-9 benzylamine 
• 122-78-1 phenylacetaldehyde 

Downstream Products

• 620-71-3 N-(phenyl)-2-methylacetamide 
• 93-98-1 N-phenyl benzoyl amide 
• 5097-82-5 5-phenyl-1H-tetrazolone 
• 603-54-3 N,N-diphenylurea 
• 62-53-3 aniline 
• 101-99-5 N-carboethoxyaniline 
• 124-38-9 carbon dioxide 
• 102-07-8 bis(diphenyl)urea 
• 10264-18-3 N-phenylpentanamide 
• 1467-21-6 N-phenyl-N'-benzylurea 
• 4559-92-6 N-phenylmorpholine-4-carboxamide 
• 131999-73-0 N-phenylcarbamoyl-glycine benzylidenehydrazide 
• 131999-71-8 N-phenylcarbamoyl-glycine hydrazide 
• 104892-36-6 5-phenyl-hydantoic acid methyl ester 

Relevant articles and documents

Copper-Catalyzed Nitrogenation of Aromatic and Aliphatic Aldehydes: A Direct Route to Carbamoyl Azides

An efficient copper-catalyzed synthesis of carbamoyl azides directly from aldehydes has been developed. Both aromatic aldehydes and aliphatic aldehydes, together with other commercially available reactants, can be used as substrates in this radical relay reaction. Broad substrate scope, simple operation, readily available reagents, and good functionality tolerance make this method very attractive.

KI Catalyzed Nitrogenation of Aldehydes and Alcohols: Direct Synthesis of Carbamoyl Azides and Ureas

An efficient KI catalyzed nitrogenation of aldehydes and alcohols for the direct synthesis of carbamoyl azides and ureas via a radical process has been developed. The simple operating procedures, the readily available starting materials including aldehydes, alcohols and amines, as well as the utility of the products all make this strategy very attractive.

Ceric ammonium nitrate (CAN) catalyzed modification of ketones via two C-C bond cleavages with the retention of the oxo-group

A simple ceric ammonium nitrate (CAN) catalyzed functionalization of ketones through double C-C bond cleavage strategy has been disclosed. This reaction provides a mild, practical method toward carbamoyl azides, which are versatile intermediates and building blocks in organic synthesis. Based on relevant mechanistic studies, a unique and plausible C-C bond and N-O bond cleavage process is proposed, where the oxyamination intermediate plays an important role in this reaction.