98391-91-4

Upstream product

• 74-85-1 ethene 
• 78-84-2 isobutyraldehyde 
• 125665-01-2 N-<(2R,3S)-3-hydroxy-2,4-dimethylpentanoyl>bornane-10,2-sultam 

Downstream Products

• 163932-35-2 (2R,3S)-2,4-dimethyl-1-(phenylthio)-3-pentanol 
• 380497-27-8 1-[(4S,5S,2R)-5-methyl-4-(methylethyl)(1,3-dioxan-2-yl)]-4-methoxybenzene 
• 1597437-38-1 C₅₀H₉₅NO₅Si₄ 
• 131043-84-0 (3R,4S,5S,6R)-3-Methoxymethoxy-2,4,6-trimethyl-pentadecan-5-ol 
• 131043-84-0 (3R,4S,5R,6S)-3-Methoxymethoxy-2,4,6-trimethyl-pentadecan-5-ol 
• 131043-84-0 (3R,4S,5R,6R)-3-Methoxymethoxy-2,4,6-trimethyl-pentadecan-5-ol 
• 120483-23-0 (S)-4-Hydroxy-1-((2S,5R,6S)-6-isopropyl-2-methoxy-5-methyl-tetrahydro-pyran-2-yl)-6-(toluene-4-sulfonyl)-hexan-2-one 
• 120483-23-0 (R)-4-Hydroxy-1-((2S,5R,6S)-6-isopropyl-2-methoxy-5-methyl-tetrahydro-pyran-2-yl)-6-(toluene-4-sulfonyl)-hexan-2-one 
• 120483-10-5 (2S,6R,8R,9S)-8-Isopropyl-9-methyl-2-[2-(toluene-4-sulfonyl)-ethyl]-1,7-dioxa-spiro[5.5]undecan-4-one 
• 120483-11-6 (2S,4S,6R,8R,9S)-8-Isopropyl-9-methyl-2-[2-(toluene-4-sulfonyl)-ethyl]-1,7-dioxa-spiro[5.5]undecan-4-ol 
• 120483-11-6 (2S,4R,6R,8R,9S)-8-Isopropyl-9-methyl-2-[2-(toluene-4-sulfonyl)-ethyl]-1,7-dioxa-spiro[5.5]undecan-4-ol 
• 113116-34-0 (R)-6-Benzyloxy-4-hydroxy-1-((2S,5R,6S)-6-isopropyl-2-methoxy-5-methyl-tetrahydro-pyran-2-yl)-hexan-2-one 
• 113116-34-0 (S)-6-Benzyloxy-4-hydroxy-1-((2S,5R,6S)-6-isopropyl-2-methoxy-5-methyl-tetrahydro-pyran-2-yl)-hexan-2-one 
• 113116-32-8 (10R,11S)-1-Benzyloxy-3-hydroxy-10,12-dimethyl-11-trimethylsilanyloxy-tridecane-5,7-dione 

Relevant academic research and scientific papers

Domino hydroformylation/enantioselective cross-aldol addition

A domino hydroformylation/enantioselective cross-aldol reaction sequence is reported. Starting from simple alkenes enantiomerically pure aldol addition products, which represent valuable building blocks for polypropionate construction, can be obtained in a one-pot operation.

Bornanesultam-directed asymmetric synthesis of crystalline, enantiomerically pure syn aldols

N-acylsultams 2 furnish, via aldolization of their enolates 16 with aldehydes, diastereomerically pure, crystalline syn aldols. The absolute configuration of the product is controlled by the choice of the enolate counterion: 16, M = B → 3; 16, M = Li or S