The photography industry has employed pyrazolidinediones as the main component in both pigments as well as thermal-based printing materials
Facile scalable reduction of N-acylated dihydropyrazoles
Scheme 1
The significance of the pyrazolidine heterocycle is evidenced by its presence as a structural subunit in a variety of compounds frequently utilized in both the photography and pharmaceutical industries.1-7 The photography industry has employed pyrazolidinediones (3) as the main component in both pigments as well as thermal-based printing materials (Scheme 1).1 Further- more, pyrazolidine compounds have been converted into azaproline amino acids (4), which have been studied upon incorporation into traditional peptides as well as small molecule peptidomimetics (5).2-6
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