Synthesis and lanthanide coordination chemistry of CMPO-decorated dibenzothiophene and DIBENZOTHIOPHENE SULFONE (cas 1016-05-3) platforms

Add time:07/20/2019    Source:sciencedirect.com

Syntheses and spectroscopic characterization data for two new hybrid chelating ligands, 4,6-bis[(diphenyl-N,N-diethylcarbamoylmethylphosphine oxide)methyl]dibenzothiophene (2) and 4,6-bis[(diphenyl-N,N-diethylcarbamoylmethylphosphine oxide)methyl]dibenzothiophene 5,5-dioxide (3), that contain two CMPO fragments grafted onto dibenzothiophene and DIBENZOTHIOPHENE SULFONE (cas 1016-05-3) platforms, respectively, are presented. Coordination chemistry with selected lanthanide nitrates is described along with a X-ray crystal structure determination for an unexpected Eu(III) complex, Eu(4)(NO3)3 that contains the intermediate ligand oxidation species 4,6-bis[(diphenyl-N,N-diethylcarbamoylmethylphosphine oxide)methyl]dibenzothiophene 5-oxide (4).

We also recommend Trading Suppliers and Manufacturers of DIBENZOTHIOPHENE SULFONE (cas 1016-05-3). Pls Click Website Link as below: cas 1016-05-3 suppliers

Prev:Improved conversion of Dibenzothiophene into sulfone by surface display of Dibenzothiophene monooxygenase (DszC) in recombinant Escherichia coli
Next:Adsorptive removal of DIBENZOTHIOPHENE SULFONE (cas 1016-05-3) from fuel oil using clay material adsorbents)