The conversion of cellulose into carboxylic acids by a drastic alkali treatment
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Add time:07/21/2019 Source:sciencedirect.com
Cotton cellulose was treated with 1 and 3 M sodium hydroxide at 170–190°C and the resulting mixtures were investigated by capillary gas-liquid chromatography-mass spectrometry. Up to 65 products were identified including mainly straight-chain and branched-chain hydroxy monocarboxylic acids and dicarboxylic acids, of which lactic, glycolic, 3-deoxytetronic, glucoisosaccharinic, 3,4-dideoxypentonic, and 3,4-dideoxyhexaric acids were the main compounds. Utilization possibilities of the acid mixtures are briefly discussed.
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