Unusual coordination mode of a 2-pyridyl ketone oxime ligand in bis(4-butylphenyl 2-pyridyl ketone oximate)palladium(II)

Add time:07/20/2019    Source:sciencedirect.com

In the complex PdL2 (HL = 4-butylphenyl 2-pyridyl ketone oxime), characterised by spectroscopic techniques and X-ray diffraction analysis, the deprotonated ligand displays a N,O coordination, with the pyridyl nitrogen and the oxime oxygen, which is without precedence in this class of compounds; 1H NMR spectra, together with structural data on PdL2, make it possible to distinguish between the N,O and N,N coordination mode in analogous compounds.

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