The coordination chemistry of 4′-(4-tert-butylphenyl)-2,2′ : 6′,2″-terpyridine—a solubilising oligopyridine
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Add time:07/18/2019 Source:sciencedirect.com
The preparation of a solubilised 2,2′ : 6′,2″-terpyridine ligand is described together with the characterisation of an unexpected intermediate. Homoleptic complexes of the solubilised ligand 4′-(4-tert-butylphenyl)-2,2′ : 6′,2″-terpyridine, 1, with cobalt(II), cobalt(III), ruthenium(II), iron(II) and nickel(II) have been prepared. The ligand is slightly electron releasing and solubilises the complexes in organic media.
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