Stable bis(diisopropylamino)cyclopropenylidene (cas 16165-40-5) (BAC) as ligand for transition metal complexes

Add time:07/23/2019    Source:sciencedirect.com

Several nickel(0), palladium(II), and rhodium(I) complexes have been prepared using for the first time the stable bis(diisopropylamino)cyclopropenylidene (BAC). Based on single crystal X-ray diffraction studies and spectroscopic data, the structural and electronic properties of these complexes are discussed. Moreover, their similarities and differences with the analogous NHC complexes are emphasized.

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