Catalysis of CC-coupling reactions by cyclopropenylidene (cas 16165-40-5) palladium complexes

Add time:07/29/2019    Source:sciencedirect.com

Several mixed palladium(II) complexes bearing 2,3-diarylcyclopropenylidene (cas 16165-40-5) ligands (aryl = phenyl, mesityl, naphthyl) and triaryl- and trialkylphosphines have been prepared. Single crystal structure details of one of the dimeric chloro-bridged complexes as well as of two monomeric phosphine substituted complexes are presented and compared with appropriate structural features of similar 2,3-diaminocyclopropenylidene- and cycloheptatrienylidene complexes. The new complexes were tested as catalysts in Suzuki–Mijaura coupling reactions with bromo- and chloroarenes and their catalytic activity compared with that of analogous NHC- and cycloheptatrienylidene complexes.

We also recommend Trading Suppliers and Manufacturers of cyclopropenylidene (cas 16165-40-5). Pls Click Website Link as below: cas 16165-40-5 suppliers

Prev:An accurate ab initio quartic force field and vibrational frequencies for cyclopropenylidene (cas 16165-40-5)
Next:New prodrugs of two pyrimidine acyclic nucleoside phosphonates: Synthesis and antiviral activity)