Unexpected Reactions of (Heptafluoro-1,4-cyclohexadien-1-yl)xenon(II) Hexafluoroarsenate with Sodium Fluoride and Antimony Pentafluoride
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Add time:07/23/2019 Source:sciencedirect.com
The reactivity of (heptafluoro-1,4-cyclohexadien-1-yl)xenon(ii) hexafluoroarsenate 1 towards a fluoride donor and acceptor has been investigated; the interaction of 1 with NaF led to perfluoro-3-methylenecyclopentene and xenon. No dication [C6F6Xe]2+ was detected by 19F NMR spectroscopy when [1-Xe + -1,4-C6F7] [AsF6]– was treated with SbF5–SO2, SbF5–SO2FCI or neat SbF5.
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