The Cobalt hydrocarbonyl. (cas 16842-03-8)catalyzed isomerization of allylbenzene
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Add time:07/20/2019 Source:sciencedirect.com
The HCo(CO)4-catalyzed isomerization of PhCD2CHCH2 carried out in the presence of an excess of p-allyltoluene gave principally trans-PhCDCHCH3. This result rules out a catalyzed [1,3] sigmatropic shift but is consistent with a 1,2-addition-elimination mechanism.
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