The isomerization and hydrogenation of the maleate-fumarate system by cobalt hydrocarbonyl
-
Add time:07/23/2019 Source:sciencedirect.com
Treatment of dimethyl maleate with DCo(CO)4 gives deuterated dimethyl fumarate and dimethyl succinate but no deuterium incorporation in the recovered maleate. The hydrogenation of dimethyl maleate to succinate proceeds via the fumarate. For the isomerization reaction, the results are best rationalized on the basis of a 1,2-cis-addition-elimination of DCo(CO)4 while the hydrogenation probably involves 1,4-addition to the fumarate.
We also recommend Trading Suppliers and Manufacturers of Cobalt hydrocarbonyl. (cas 16842-03-8). Pls Click Website Link as below: cas 16842-03-8 suppliers
Prev:Theoretical investigation on hydroformylation reactions
Next:Effect of La2O3-dopping on the Al2O3 supported cobalt catalyst for Fischer-Tropsch synthesis) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Modified copper-cobalt-chromium oxide catalysts for CO2 hydrogenation to mixed alcohols(C1-Cθ)07/28/2019
- Catalysis by Cobalt Carbonyls07/27/2019
- Direct conversion of syngas to isoparaffins over hierarchical beta zeolite supported cobalt catalyst for Fischer-Tropsch synthesis07/26/2019
- Surface modifications of cobalt Fischer Tropsch catalyst followed by operando DRIFT and chemometrics07/25/2019
- Effect of La2O3-dopping on the Al2O3 supported cobalt catalyst for Fischer-Tropsch synthesis07/24/2019
- Theoretical investigation on hydroformylation reactions07/22/2019
- The Cobalt hydrocarbonyl. (cas 16842-03-8)catalyzed isomerization of allylbenzene07/20/2019
-
Health and Chemical more >