Metal-free, regio- and stereoselective S-methylation/phenylation of allyl halides using sulfoxides as sulfenylating agent

Add time:07/23/2019    Source:sciencedirect.com

A DCP promoted metal-free, regio and stereoselective S-methylation/phenylation of allyl halides using sulfoxides as sulfenylating agent is described. A variety of multifunctional allyl halides underwent S-methylation and S-phenylation by using dimethyl sulfoxide (DMSO) and diphenyl sulfoxide (DPSO) under the reaction conditions employed to provide the resulting thioethers in good to excellent yields.

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