5′-O-demethyl-8-O-methyl-7-epi-dioncophylline A (cas 60142-17-8) and its ‘regularly’ configurated atropisomer from Triphyophyllum peltatum

Add time:07/14/2019    Source:sciencedirect.com

The isolation and structure elucidation of two new minor naphthylisoquinoline alkaloids from the stem bark of Triphyophyllum peltatum is described. From extended spectroscopic investigations, mainly NMR and CD spectroscopy, one of the alkaloids is deduced to be 5′-O-demethyl-8-O-methyl-7-epi-dioncophylline A. This new natural product is, thus, the first dioncophylline A analogous naphthylisoquinoline alkaloid from T. peltatum with an opposite configuration at the biaryl axis. Moreover, low amounts of an additional new alkaloid were isolated, whose spectral data suggest 5′-O-demethyl-8-O-methyl-dioncophylline A, i.e. the corresponding ‘normal’ atropodiastereomer.

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