Photoactivated telomerization of 1,1,3,3-TETRAMETHYL-1,3-DISILACYCLOBUTANE (cas 1627-98-1) with hydrosilanes by Pt(acac)2 and its competition with hydrosilylation addition

Add time:07/25/2019    Source:sciencedirect.com

Telomerization of 1,1,3,3-TETRAMETHYL-1,3-DISILACYCLOBUTANE (cas 1627-98-1) with hydrosilanes is facilitated by UV irradiation in the presence of Pt(acac)2. When olefin is also present, photoactivated hydrosilylation competes with telomerization. The dependence of product distribution on the reactivity of the hydrosilanes and the olefins was studied.

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