Metathesis of functionalized olefins with WCl6-(or WOCl4-) 1,1,3,3-TETRAMETHYL-1,3-DISILACYCLOBUTANE (cas 1627-98-1) catalyst

Add time:07/26/2019    Source:sciencedirect.com

Several homogeneous and heterogeneous catalysts have been used for the metathesis of functionalized olefins. The homogeneous catalyst WCl6- (or WOCl4-) 1,1,3,3-TETRAMETHYL-1,3-DISILACYCLOBUTANE (cas 1627-98-1) allows the metathesis of various functionalized olefins with short chain length (esters of fatty acids, unsaturated nitriles, etc.). Self-and co-metathesis of allyl cyanide, ethyl 4-pentenoate and allyltrimethylsilane with linear and cyclic olefins occurs with high yields and selectivity. These reactions allow the production of silyl derivatives of unsaturated nitriles and esters by single-step reactions.

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