Photoelectron transfer induced decarboxylation of substituted carboxylic acids across a liquid/liquid interface
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Add time:07/31/2019 Source:sciencedirect.com
Methylene blue photocatalyzed electron transfer reactions of some phenoxyacetic acid derivatives and N-phenylglycine across a liquid/liquid interface led to their efficient decarboxylation. Nanosecond laser flash photolysis studies of this process, in a reverse micellar system of Aerosol-OT (AOT)-benzene-water indicated that the liquid/liquid interface acts as a barrier in controlling the energy wasting back electron transfer. Intramolecular CC bond forming reactions of these radicals were utilized for the synthesis of various chroman derivatives.
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