Nonplanar cyclobutane—II

Add time:07/25/2019    Source:sciencedirect.com

NMR spectra and basic equilibration of cis and trans methyl-3-isopropylcyclobutanecarboxylate are reported. Treatment of the nonplanar cyclobutane system by analogy with cyclohexane is potentially possible, but limited by (1) greater dependence of ring puckering on substituents; and (2) intervention of planar conformers.

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