Synthesis and crystal structure of maleonitriledithiolate metal complexes with N-methylacridine (cas 13367-81-2) as cations

Add time:07/24/2019    Source:sciencedirect.com

The synthesis of [N-MeA]2[M(mnt)2] (N-MeA=N-methylacridine; M=Ni (II), Zn (II), Cu (II) and Cd (II); mnt=maleonitriledithiolate) and crystal structure analysis of the Ni (1) and Zn (2) complexes are reported. The conductivities of almost all the complexes under 4 MPa pressure are above 10−5 S cm−1, which are characteristic of intrinsic semi-conductors. The complexes exhibit charge transfer transitions in both their absorption spectra and fluorescence spectroscopy.

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