Raman spectrum of Cu2CdSnSe4 stannite (cas 12019-29-3) structure semiconductor compound

Add time:07/28/2019    Source:sciencedirect.com

Raman spectrum of Cu2CdSnSe4 quaternary semiconductor compounds with tetragonal stannite (cas 12019-29-3)-type structure (space group I4¯2m), a material which has been recognized recently as a potential candidate for thermoelectric applications, has been studied. Most of the fourteen Raman lines expected for this compound according to group theory analysis were observed in the spectrum. Besides to the two strongest A1-symmetry stannite modes at 172 and 192 cm−1 originated from the motion of Se anion around the Cu and Sn cations which remain at rest, the leftover observed Raman lines were tentatively assigned to specific eigenmodes of the stannite crystal structure by comparing these line frequencies with those obtained for this compound from IR measurements as well as with those calculated Raman modes for the Cu2ZnSnSe4 stannite-compound reported in the literature. Two spurious Raman lines related to the presence in this compound of SnSe and SnSe2 minority secondary phases have also been found in the Raman spectrum.

We also recommend Trading Suppliers and Manufacturers of stannite (cas 12019-29-3). Pls Click Website Link as below: cas 12019-29-3 suppliers

Prev:Optical properties of the mechanochemically synthesized Cu2FeSnS4 (stannite (cas 12019-29-3)) nanocrystals: Raman study
Next:XAFS study of kesterite, kuramite and stannite (cas 12019-29-3) type alloys)