Dipalladium(I) complexes of ortho- and para-functionalized 1,3-bis(aryl)triazenide ligands: Synthesis, structure and catalytic activity

Add time:07/25/2019    Source:sciencedirect.com

The synthesis and characterization of a series dipalladium(I) complexes of formulae [Pd{1-[2′-(methoxycarbonyl)phenyl]-3-[4′-X-phenyl]triazenide}]2 [X = F (4), Cl (5), Br (6)] are reported. The crystal structure of complex 4 was determined by X-ray diffraction studies. The previously reported dipalladium(I) 1–3 as well as the new complexes 4–6 were used as catalysts in the Heck and Suzuki couplings of different p-substituted bromobenzenes.

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