Asymmetric reductions of (trifluoroacetyl)biphenyl derivatives with bakers' yeast and with Geotrichum candidum acetone powder
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Add time:07/25/2019 Source:sciencedirect.com
The bakers' yeast reduction of (trifluoroacetyl)biphenyl derivatives produces (R)-trifluoromethyl biphenylyl carbinols in high enantioselectivity, whereas the reduction of the same derivatives with Geotrichum candidum acetone powder gives the corresponding (S)-carbinols in excellent yields and enantioselectivity.
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