Unusual phase transition mechanism in rare-earth ethylsulfates

Add time:07/26/2019    Source:sciencedirect.com

A hypothesis is put forward that at pressure 30 kbar f-orbitals begin to participate in generation of a chemical bond between a rare-earth ion and oxygen. This phenomenon is presumed to be responsible for spectral changes observed in praseodymium ethylsulfate at its compression.

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