Asymmetric synthesis of (3R,5R)- and (3S,5S)-2,6-Dimethylheptane (cas 1072-05-5)-3,5-diol, useful C2 chiral auxiliaries

Add time:07/25/2019    Source:sciencedirect.com

(R,R)- and (S,S)-2,6-Dimethylheptane-3,5-diol, which are useful C2 chiral auxiliaries, have been both synthesized in high optical purity from 2,6-dimethylheptane-3,5-dione, by using as key step a Sharpless kinetic resolution.

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