Photocatalytic hydrogen-evolution dimerization of styrenes to synthesize 1,2-dihydro-1-arylnaphthalene derivatives using Acr+-Mes and cobaloxime catalysts

Add time:07/27/2019    Source:sciencedirect.com

We report a hydrogen-evolution dimerization of styrenes via the synergistic merger of Acr+-Mes photocatalyst and cobaloxime proton reduction catalysts. By utilizing this dual catalyst system, 1,2-dihydro-1-arylnaphthalene derivatives can be directly constructed from commercially available styrenes. Our reaction proceeds smoothly under mild conditions without the need for oxidants or hydrogen atom transfer reagents, and the sole byproduct is hydrogen gas. Mechanistic investigation suggests that the reaction is initiated by photoinduced electron transfer under visible-light irradiation.

We also recommend Trading Suppliers and Manufacturers of 1,2-dihydro-1-(o-methoxyphenyl)-5H-tetrazole-5-thione (cas 15182-67-9). Pls Click Website Link as below: cas 15182-67-9 suppliers

Prev:A photoelectron study (HeI, HeII) of the tautomeric equilibrium of chloro- and bromo-1,2,4-triazoles
Next:Remote regio- and stereocontrol by the sulfinyl group: Diels–Alder reaction of sulfinyl dienols and 8,8-dimethylnaphthalene-1,4,5(8H)-trione)