Highly efficient removal of Ceftiofur sodium (cas 104010-37-9) using a superior hydroxyl group functionalized ionic liquid-modified polymer

Add time:07/29/2019    Source:sciencedirect.com

The occurrence of cephalosporin antibiotics in water resources has caused increasing concerns about their potential effects on ecosystem and human health. However, reports on the efficient removal of these antibiotics are limited. In this work, a superior hydroxyl-functionalized ionic liquid based polymer (PS-[Hemim][Cl]) was prepared for highly efficient removal of Ceftiofur sodium (cas 104010-37-9) (CFS) antibiotic from aqueous solutions, and the effect of various factors on the adsorption was investigated. It was found that the PS-[Hemim][Cl] exhibited a super-high adsorption capacity of 1260.5 mg/g for CFS within 60 min and kept high removal efficiency in a wide range of antibiotic concentrations from 5 ppb level to 1000 mg/L. Even the concentration of common inorganic ions was 1000 times higher than that of CFS, the adsorption efficiency remained above 93%. At the same time, the PS-[Hemim][Cl] showed excellent adsorption performance for the antibiotics with similar structure to CFS. Compared with commercially available adsorbents, the adsorption capacity of PS-[Hemim][Cl] for CFS was 4–468 times higher under the same experimental conditions. The application of PS-[Hemim][Cl] to real wastewater containing different concentrations of CFS was investigated and promising results were reported. Additionally, preliminary mechanism studies suggested that electrostatic attraction, hydrogen bond and ion exchange synergistically contributed to the highly efficient adsorption of CFS.

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