A novel aminomethylation reaction of gaseous alkanes with tert-methylamine N-oxides via CH bond activation by copper(II) salts

Add time:07/28/2019    Source:sciencedirect.com

The Cu(OAc)2/CF3COOH (TFA) system catalyzes the aminomethylation of gaseous alkanes such as propane and ethane with trimethylamine N-oxide to give N,N-dimethylisobutylamine (1) and N,N-dimethylpropylamine (7), respectively. The corresponding trifluoroacetates are also formed as by-products from the reactions of methane and propane.

We also recommend Trading Suppliers and Manufacturers of N-ISOBUTYLMORPHOLINE (cas 10315-98-7). Pls Click Website Link as below: cas 10315-98-7 suppliers

Prev:A convenient synthesis of 2,2-difluoro enol silyl ethers from chlorodifluoromethyl ketones
Next:Discovery and Characterization of a Nitroreductase Capable of Conferring Bacterial Resistance to Chloramphenicol)