Synthesis, characterization and photocatalytic activity of a dinuclear thiocyanate bridged cadmium(II) Schiff base complex
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Add time:07/29/2019 Source:sciencedirect.com
A dinuclear centrosymmetric cadmium(II) Schiff base complex, [Cd2(L)2(μ-1,3-SCN)2(CH3OH)2], {HL = 2-(3-(methylamino)propyliminomethyl)-4,6-dichlorophenol} has been synthesized and characterized. X-ray crystallography has confirmed its structure. The complex crystallizes in monoclinic space group C2/c with cell dimensions, a = 26.161(1) Å, b = 8.9412(3) Å, c = 18.9687(8) Å, β = 129.202(1)°. Extended supra-molecular assemblies were generated through weak non-covalent interactions. The application of the complex as a photocatalyst for the decomposition of organic dye in visible light has been explored.
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