Nucleophilic substitution at the bridgehead of 1,4-dihalobicyclo[2.2.2]octanes : An abnormal leaving group mobility order

Add time:07/28/2019    Source:sciencedirect.com

Stannylation of 1-bromo- and 1-chloro-4-iodobicyclo[2.2.2]octane with (trimethyltin) lithium indicate an abnormal leaving group mobility (Br>I>Cl).

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